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• W2280552441 abstract "Abstract A novel electrochemical route to generate nitriles from aldehydes under mild conditions using a catalytic amount of TEMPO (2,2,6,6-tetramethylpiperidinyl-l-oxy) as the mediator and hexamethyldisilazane as the nitrogen source in the presence of acetic acid has been developed. A variety of aromatic, heteroaromatic and aliphatic aldehydes have been converted to their corresponding nitriles in good to excellent yields. A plausible reaction mechanism is proposed based on the cyclic voltammetry, in situ FTIR and the identification of intermediates." @default.
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• W2280552441 date "2016-03-01" @default.
• W2280552441 modified "2023-10-17" @default.
• W2280552441 title "Electrochemical synthesis of nitriles from aldehydes using TEMPO as a mediator" @default.
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• W2280552441 doi "https://doi.org/10.1016/j.elecom.2016.01.011" @default.
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