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• W2281328498 endingPage "A1990" @default.
• W2281328498 startingPage "A1983" @default.
• W2281328498 abstract "The Mossbauer effect for ${mathrm{Fe}}^{57m}$ in the BaTi${mathrm{O}}_{3}$ lattice has been studied from 300 to 1200ifmmode^circelsetextdegreefi{}K with particular emphasis on the region near the Curie temperature. The Mossbauer probe seems to serve as a useful tool for the study of ferroelectrics. The electric-field gradient as seen by the probe at room temperature is -0.52ifmmodetimeselsetexttimesfi{}${10}^{14}$ esu ${mathrm{cm}}^{ensuremath{-}3}$ and is closely proportional to $P_{s}^{}{}_{}{}^{2}$ as the spontaneous polarization ${P}_{s}$ varies with temperature. The strength of the resonant absorption was also determined as a function of temperature in the region above ${T}_{c}$. Much above ${T}_{c}$ these measurements are compatible with a Debye temperature of 450ifmmode^circelsetextdegreefi{}K. However, as the Curie temperature is approached, the Lamb-Mossbauer factor decreases appreciably. These results are discussed in the light of Cochran's theory of ferroelectricity. From the isomer shift at room temperature (0.50ifmmodepmelsetextpmfi{}0.02 mm/sec with respect to 310 stainless steel) the over-all degree of ionicity is estimated to be 60ifmmodepmelsetextpmfi{}20%. The temperature shift shows a discontinuity at ${T}_{c}$ and is attributed to the change in covalent binding." @default.
• W2281328498 created "2016-06-24" @default.
• W2281328498 creator A5001120006 @default.
• W2281328498 creator A5072443417 @default.
• W2281328498 date "1965-09-13" @default.
• W2281328498 modified "2023-09-27" @default.
• W2281328498 title "Mössbauer Effect in Ferroelectric BaTi<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>" @default.
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• W2281328498 doi "https://doi.org/10.1103/physrev.139.a1983" @default.
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