Matches in SemOpenAlex for { <https://semopenalex.org/work/W2281431013> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2281431013 endingPage "10021" @default.
- W2281431013 startingPage "10016" @default.
- W2281431013 abstract "Microwave spectra for a higher-energy conformer of cyclopropanecarboxylic acid (CPCA) were measured using a Flygare-Balle-type pulsed-beam Fourier transform microwave spectrometer. The rotational constants (in megahertz) and centrifugal distortion constants (in kilohertz) for this higher-energy conformer are A = 7452.3132(57), B = 2789.8602(43), C = 2415.0725(40), DJ = 0.29(53), and DJK = 2.5(12). Differences between rotational constants for this excited-state conformation and the ground state are primarily due to the acidic OH bond moving from a position cis relative to the cyclopropyl group about the C1-C9 bond to the more stable trans conformation. Calculations indicate that the relative abundance of the higher-energy state should be 15% to 17% at room temperature, but the observed relative abundance for the supersonic expansion conditions is about 1%. The measurements of rotational transitions for the trans form of CPCA were extended to include all of the unique (13)C singly substituted positions. These measurements, along with previously measured transitions of the parent and -OD isotopologues, were used to determine a best-fit gas-phase structure." @default.
- W2281431013 created "2016-06-24" @default.
- W2281431013 creator A5022328909 @default.
- W2281431013 creator A5076633958 @default.
- W2281431013 creator A5091316373 @default.
- W2281431013 date "2015-09-21" @default.
- W2281431013 modified "2023-10-16" @default.
- W2281431013 title "Microwave Spectrum for a Second Higher Energy Conformer of Cyclopropanecarboxylic Acid and Determination of the Gas Phase Structure of the Ground State" @default.
- W2281431013 cites W1922762817 @default.
- W2281431013 cites W1972346855 @default.
- W2281431013 cites W1972475348 @default.
- W2281431013 cites W1999714839 @default.
- W2281431013 cites W2019169350 @default.
- W2281431013 cites W2019688390 @default.
- W2281431013 cites W2043530474 @default.
- W2281431013 cites W2051978409 @default.
- W2281431013 cites W2069723789 @default.
- W2281431013 cites W2083000858 @default.
- W2281431013 cites W2089933239 @default.
- W2281431013 cites W2111098227 @default.
- W2281431013 cites W2214894048 @default.
- W2281431013 cites W222855861 @default.
- W2281431013 cites W2952979445 @default.
- W2281431013 cites W83431813 @default.
- W2281431013 cites W1545045768 @default.
- W2281431013 doi "https://doi.org/10.1021/acs.jpca.5b06733" @default.
- W2281431013 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26359681" @default.
- W2281431013 hasPublicationYear "2015" @default.
- W2281431013 type Work @default.
- W2281431013 sameAs 2281431013 @default.
- W2281431013 citedByCount "2" @default.
- W2281431013 countsByYear W22814310132015 @default.
- W2281431013 countsByYear W22814310132019 @default.
- W2281431013 crossrefType "journal-article" @default.
- W2281431013 hasAuthorship W2281431013A5022328909 @default.
- W2281431013 hasAuthorship W2281431013A5076633958 @default.
- W2281431013 hasAuthorship W2281431013A5091316373 @default.
- W2281431013 hasConcept C113196181 @default.
- W2281431013 hasConcept C121332964 @default.
- W2281431013 hasConcept C127124265 @default.
- W2281431013 hasConcept C1276947 @default.
- W2281431013 hasConcept C13934619 @default.
- W2281431013 hasConcept C161790260 @default.
- W2281431013 hasConcept C169146920 @default.
- W2281431013 hasConcept C178790620 @default.
- W2281431013 hasConcept C181500209 @default.
- W2281431013 hasConcept C184779094 @default.
- W2281431013 hasConcept C185592680 @default.
- W2281431013 hasConcept C18705241 @default.
- W2281431013 hasConcept C2777949474 @default.
- W2281431013 hasConcept C31100168 @default.
- W2281431013 hasConcept C32909587 @default.
- W2281431013 hasConcept C4839761 @default.
- W2281431013 hasConcept C69523127 @default.
- W2281431013 hasConceptScore W2281431013C113196181 @default.
- W2281431013 hasConceptScore W2281431013C121332964 @default.
- W2281431013 hasConceptScore W2281431013C127124265 @default.
- W2281431013 hasConceptScore W2281431013C1276947 @default.
- W2281431013 hasConceptScore W2281431013C13934619 @default.
- W2281431013 hasConceptScore W2281431013C161790260 @default.
- W2281431013 hasConceptScore W2281431013C169146920 @default.
- W2281431013 hasConceptScore W2281431013C178790620 @default.
- W2281431013 hasConceptScore W2281431013C181500209 @default.
- W2281431013 hasConceptScore W2281431013C184779094 @default.
- W2281431013 hasConceptScore W2281431013C185592680 @default.
- W2281431013 hasConceptScore W2281431013C18705241 @default.
- W2281431013 hasConceptScore W2281431013C2777949474 @default.
- W2281431013 hasConceptScore W2281431013C31100168 @default.
- W2281431013 hasConceptScore W2281431013C32909587 @default.
- W2281431013 hasConceptScore W2281431013C4839761 @default.
- W2281431013 hasConceptScore W2281431013C69523127 @default.
- W2281431013 hasFunder F4320306196 @default.
- W2281431013 hasFunder F4320337393 @default.
- W2281431013 hasIssue "39" @default.
- W2281431013 hasLocation W22814310131 @default.
- W2281431013 hasLocation W22814310132 @default.
- W2281431013 hasOpenAccess W2281431013 @default.
- W2281431013 hasPrimaryLocation W22814310131 @default.
- W2281431013 hasRelatedWork W1980971123 @default.
- W2281431013 hasRelatedWork W1999013594 @default.
- W2281431013 hasRelatedWork W2021632438 @default.
- W2281431013 hasRelatedWork W2033844151 @default.
- W2281431013 hasRelatedWork W2034344584 @default.
- W2281431013 hasRelatedWork W2048796505 @default.
- W2281431013 hasRelatedWork W2071466038 @default.
- W2281431013 hasRelatedWork W2081062350 @default.
- W2281431013 hasRelatedWork W2092752668 @default.
- W2281431013 hasRelatedWork W2281431013 @default.
- W2281431013 hasVolume "119" @default.
- W2281431013 isParatext "false" @default.
- W2281431013 isRetracted "false" @default.
- W2281431013 magId "2281431013" @default.
- W2281431013 workType "article" @default.