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- W2282364578 abstract "A unique strategy for the regiospecific synthesis of bicyclic furopyran derivatives has been developed via a gold(I)-catalyzed propargyl-Claisen rearrangement/6-endo-trig cyclization of propargyl vinyl ethers. The introduction of angle strain into the substrates significantly altered the reaction's regioselectivity. Insight into the regioselectivity of the cycloisomerization was obtained with density functional theory calculations." @default.
- W2282364578 created "2016-06-24" @default.
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- W2282364578 date "2016-02-03" @default.
- W2282364578 modified "2023-10-16" @default.
- W2282364578 title "Gold(I)-Catalyzed Angle Strain Controlled Strategy to Furopyran Derivatives from Propargyl Vinyl Ethers: Insight into the Regioselectivity of Cycloisomerization" @default.
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- W2282364578 doi "https://doi.org/10.1021/acs.orglett.5b03641" @default.
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