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• W2282744227 abstract "The crystallization sequence and metasomatic alteration of spodumene (LiAlSizOe), montebrasite (LiAIPO4(OH,F)), and lithiophilite (Li(Mn,Fe)PO+) are described for nine zoned lithium pegmatites in the White Picacho district, Arizona. The observed crystallization trends suggest a progressive increase in the activities of lithium species (spodumene follows microcline as the principal alkali aluminosilicate), as well as an increase in the activities of the acidic volatiles phosphorus and fluorine (montebrasite succeeds spodumene as the stable primary lithium phase). Much of the lithiophilite occurs with columbite, apatite, beryl, zircon, and tourmaline in cleavelandite complexes that formed in part at the expense of quartz-spodumene pegmatite. Fracture-controlled pseudomorphic alteration of the primary lithium minerals is widespread and apparently is the result of subsolidus reactions with residual pegmatitic fluids. Spodumene has been replaced by eucryptite, albite, and micas. Alteration products of montebrasite include low-fluorine secondary montebrasite, crandallite (tentative), hydroxylapatite, muscovite, brazilianite, augelite (tentative), scorzalite, kulanite, wyllieite, and carbonate-apatite. Secondary phases identified in altered lithiophilite include hureaulite, triploidite, eosphorite, robertsite, fillowite, wyllieite, dickinsonite, fairfieldite, Mn-chlorapatite, and rhodochrosite. Initial subsolidus metasomatism of the lithium minerals took place in an alkaline environment, as evidenced by albitization of spodumene and calcium metasomatism of the phosphates. The formation of secondary micas in spodumene, montebrasite, tourmaline, and much feldspar reflects a change from alkaline to relatively acidic postmagmatic fluids, as (K+H)-metasomatism produced greisen-like or sericitic alteration. The abundance of minerals containing Li, Be, Mn, Nb, Ta, and Bi indicate that these pegmatites originated from a highly differentiated granitic source. These pegmatites were not fluorine-rich, as evidenced by the low fluorine contents of primary and secondary montebrasite, by the formation of OH- and Cl-apatites, and by the absence of topaz and the rarity of lepidolite, triplite, and fluorite." @default.
• W2282744227 created "2016-06-24" @default.
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• W2282744227 date "1982-02-01" @default.
• W2282744227 modified "2023-09-23" @default.
• W2282744227 title "Alteration of spodumene, montebrasite and lithiophilite in pegmatites of the White Picacho District, Arizona" @default.
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