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- W2282749541 abstract "Abstract The application of thermally and chemically stable nitroxide free radicals to a variety of motional problems in polymeric systems has been investigated. Solvents do not cause significant motion in glassy polymers until the glass transition is lowered to the temperature of measurement. With nonsolvents the results depend on the nature of the sample preparation as well as on the polymer-solvent pair. Molecular motion at the surface of a polymer immersed in a nonsolvent was investigated by means of surface-labeled latex spheres. The application of nitroxides as spin labels to the measurement of translational diffusion coefficients is explored and discussed. Finally, the application of the technique to adsorption and motion of surfactants and polymers onto surfaces is reported." @default.
- W2282749541 created "2016-06-24" @default.
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- W2282749541 date "1975-11-01" @default.
- W2282749541 modified "2023-09-24" @default.
- W2282749541 title "The Use of Stable Free Radicals to Determine Motion in Polymeric Systems" @default.
- W2282749541 doi "https://doi.org/10.5254/1.3539686" @default.
- W2282749541 hasPublicationYear "1975" @default.
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