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- W2282905087 abstract "A rigorous theoretical framework is developed for a generalized local-frame-transformation theory (GLFT). The GLFT is applicable to the following systems: Rydberg atoms or molecules in an electric field and negative ions in any combination of electric and/or magnetic fields. A first test application to the photoionization spectra of Rydberg atoms in an external electric field demonstrates dramatic improvement over the first version of the local-frame-transformation theory developed initially by U. Fano [Phys. Rev. A 24, 619 (1981)] and D. A. Harmin [Phys. Rev. A 26, 2656 (1982)]. This revised GLFT theory yields nontrivial corrections because it now includes the full on-shell Hilbert space without adopting the truncations in the original theory. Comparisons of the semianalytical GLFT Stark spectra with ab initio numerical simulations yield errors in the range of a few tens of MHz, an improvement over the original Fano-Harmin theory, whose errors are 10--100 times larger. Our analysis provides a systematic pathway to precisely describe the corresponding photoabsorption spectra that should be accurate enough to meet most modern experimental standards." @default.
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- W2282905087 date "2016-07-20" @default.
- W2282905087 modified "2023-10-15" @default.
- W2282905087 title "Generalized local-frame-transformation theory for excited species in external fields" @default.
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- W2282905087 doi "https://doi.org/10.1103/physreva.94.013419" @default.
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