Matches in SemOpenAlex for { <https://semopenalex.org/work/W2283219617> ?p ?o ?g. }
- W2283219617 endingPage "576" @default.
- W2283219617 startingPage "567" @default.
- W2283219617 abstract "Abstract A new biphenol, 3‐pentadecyl 4,4′‐biphenol, was synthesized starting from 3‐pentadecylphenol and was polycondensed with 4,4′‐difluorobenzophenone, 1,3‐bis(4‐fluorobenzoyl)benzene and bis(4‐fluorophenyl)sulfone to obtain poly(arylene ether)s with biphenylene linkages in the backbone and pendent pentadecyl chains. Inherent viscosities and number‐average molecular weights ( M n ) of the poly(arylene ether)s were in the range 0.50 − 0.81 dL g −1 and 2.2 × 10 4 − 8.3 × 10 4 , respectively. Detailed NMR spectroscopic studies of the poly(arylene ether)s indicated the presence of constitutional isomerism which existed because of the non‐symmetrical structure of 3‐pentadecyl 4,4′‐biphenol. The poly(arylene ether)s readily dissolved in common organic solvents such as dichloromethane, chloroform and tetrahydrofuran and could be cast into tough, transparent and flexible films from their chloroform solutions. The poly(arylene ether)s exhibited T g values in the range 35–60 °C which are lower than that of reference poly(arylene ether)s without pentadecyl chains. The 10% decomposition temperatures ( T 10 ) of the poly(arylene ether)s were in the range 410–455 °C indicating their good thermal stability. A gas permeation study of poly(ether sulfone) containing pendent pentadecyl chains revealed a moderate increase in permeability for helium, hydrogen and oxygen. However, there was a large increase in permeability for carbon dioxide which could be attributed to the internal plasticization effect of pendent pentadecyl chains. © 2016 Society of Chemical Industry" @default.
- W2283219617 created "2016-06-24" @default.
- W2283219617 creator A5003503967 @default.
- W2283219617 creator A5031023715 @default.
- W2283219617 creator A5033875565 @default.
- W2283219617 creator A5041598207 @default.
- W2283219617 creator A5068724947 @default.
- W2283219617 date "2016-03-16" @default.
- W2283219617 modified "2023-10-11" @default.
- W2283219617 title "Synthesis and properties of poly(arylene ether)s based on 3-pentadecyl 4,4'-biphenol" @default.
- W2283219617 cites W1509233179 @default.
- W2283219617 cites W1524814509 @default.
- W2283219617 cites W1928764920 @default.
- W2283219617 cites W1964137429 @default.
- W2283219617 cites W1965245283 @default.
- W2283219617 cites W1970381834 @default.
- W2283219617 cites W1971835158 @default.
- W2283219617 cites W1979182213 @default.
- W2283219617 cites W1980477160 @default.
- W2283219617 cites W1980936127 @default.
- W2283219617 cites W1986163523 @default.
- W2283219617 cites W1993364914 @default.
- W2283219617 cites W1994098890 @default.
- W2283219617 cites W1997159316 @default.
- W2283219617 cites W2002745039 @default.
- W2283219617 cites W2004395520 @default.
- W2283219617 cites W2005462890 @default.
- W2283219617 cites W2006274586 @default.
- W2283219617 cites W2008481284 @default.
- W2283219617 cites W2010954191 @default.
- W2283219617 cites W2013328512 @default.
- W2283219617 cites W2022350167 @default.
- W2283219617 cites W2024453109 @default.
- W2283219617 cites W2028711818 @default.
- W2283219617 cites W2029386103 @default.
- W2283219617 cites W2030656086 @default.
- W2283219617 cites W2031694548 @default.
- W2283219617 cites W2032143406 @default.
- W2283219617 cites W2036904978 @default.
- W2283219617 cites W2037438535 @default.
- W2283219617 cites W2042709311 @default.
- W2283219617 cites W2043377794 @default.
- W2283219617 cites W2043485767 @default.
- W2283219617 cites W2056216678 @default.
- W2283219617 cites W2070105486 @default.
- W2283219617 cites W2075523025 @default.
- W2283219617 cites W2078771835 @default.
- W2283219617 cites W2089761622 @default.
- W2283219617 cites W2091532937 @default.
- W2283219617 cites W2103741598 @default.
- W2283219617 cites W2126142728 @default.
- W2283219617 cites W2130565152 @default.
- W2283219617 cites W2135318252 @default.
- W2283219617 cites W2138009027 @default.
- W2283219617 cites W2143856302 @default.
- W2283219617 cites W2145701707 @default.
- W2283219617 cites W2146176271 @default.
- W2283219617 cites W2150050752 @default.
- W2283219617 cites W2154980481 @default.
- W2283219617 cites W2221022413 @default.
- W2283219617 cites W2884857113 @default.
- W2283219617 cites W4246119026 @default.
- W2283219617 doi "https://doi.org/10.1002/pi.5095" @default.
- W2283219617 hasPublicationYear "2016" @default.
- W2283219617 type Work @default.
- W2283219617 sameAs 2283219617 @default.
- W2283219617 citedByCount "6" @default.
- W2283219617 countsByYear W22832196172017 @default.
- W2283219617 countsByYear W22832196172019 @default.
- W2283219617 countsByYear W22832196172020 @default.
- W2283219617 countsByYear W22832196172022 @default.
- W2283219617 crossrefType "journal-article" @default.
- W2283219617 hasAuthorship W2283219617A5003503967 @default.
- W2283219617 hasAuthorship W2283219617A5031023715 @default.
- W2283219617 hasAuthorship W2283219617A5033875565 @default.
- W2283219617 hasAuthorship W2283219617A5041598207 @default.
- W2283219617 hasAuthorship W2283219617A5068724947 @default.
- W2283219617 hasConcept C178790620 @default.
- W2283219617 hasConcept C185592680 @default.
- W2283219617 hasConcept C188027245 @default.
- W2283219617 hasConcept C192562407 @default.
- W2283219617 hasConcept C2778806918 @default.
- W2283219617 hasConcept C2779843779 @default.
- W2283219617 hasConcept C2780263894 @default.
- W2283219617 hasConcept C2780407432 @default.
- W2283219617 hasConcept C2781076698 @default.
- W2283219617 hasConcept C59061564 @default.
- W2283219617 hasConceptScore W2283219617C178790620 @default.
- W2283219617 hasConceptScore W2283219617C185592680 @default.
- W2283219617 hasConceptScore W2283219617C188027245 @default.
- W2283219617 hasConceptScore W2283219617C192562407 @default.
- W2283219617 hasConceptScore W2283219617C2778806918 @default.
- W2283219617 hasConceptScore W2283219617C2779843779 @default.
- W2283219617 hasConceptScore W2283219617C2780263894 @default.
- W2283219617 hasConceptScore W2283219617C2780407432 @default.
- W2283219617 hasConceptScore W2283219617C2781076698 @default.
- W2283219617 hasConceptScore W2283219617C59061564 @default.
- W2283219617 hasIssue "5" @default.