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- W2283800104 abstract "Despite wide studies of Na0.5Bi0.5TiO3, structure of this material and its connection with the observed physical properties still raise numerous questions due to mutually contradicting results obtained. Here, structure and dielectric properties of poled and unpoled Na0.5Bi0.5TiO3-CaTiO3 solid solutions are studied, projecting the obtained concentration dependence of structure and dielectric properties on pure Na0.5Bi0.5TiO3 as the end member of this material group. X-ray diffraction patterns for Na0.5Bi0.5TiO3-CaTiO3 solid solutions reveal dominating of an orthorhombic Pnma phase, even for the compositions approaching the end composition (Na0.5Bi0.5TiO3), whereas structure of pure Na0.5Bi0.5TiO3 can be considered, assuming coexistence of rhombohedral and orthorhombic phases. This allows one to avoid appearance of a large difference of rhombohedral distortions between the unpoled and poled Na0.5Bi0.5TiO3, if the rhombohedral distortion is calculated as for single R3c phase. Features of dielectric permittiv..." @default.
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- W2283800104 date "2016-02-21" @default.
- W2283800104 modified "2023-10-14" @default.
- W2283800104 title "Structure and dielectric properties of Na<sub>0.5</sub>Bi<sub>0.5</sub>TiO<sub>3</sub>-CaTiO<sub>3</sub> solid solutions" @default.
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- W2283800104 doi "https://doi.org/10.1063/1.4942221" @default.
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