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- W2284070931 abstract "The system diethylzinc/optically active alcohol was examined as catalyst for asymmetric-selective polymerization of propylene oxide. Optically active alcohols with rigid structure are effective for the asymmetric selection. D(–)-1-Methoxypropanol-2 as well as poly(D-propylene oxide) of low molecular weight with hydroxyl end groups select L(–)-propylene oxide. „Catalyst control”︁ mechanism of the stereoselection in the polymerization is suggested on this and other bases. Katalysatorsysteme aus Diäthylzink und optisch aktivem Alkohol wurden auf ihre Eignung für die asymmetrisch-selektive Polymerisation von Propylenoxid untersucht. Alkohole mit Brückenstruktur sind besonders wirksam. D(–)-1-Methoxypropanol-2 wie auch Poly-D-propylenoxid von niedrigem Molekulargewicht und mit OH-Endgruppen wählen das L(–)-Propylenoxid aus. Ein „Catalyst-Control”︁-Mechanismus wird für diese und andere Fälle vorgeschlagen." @default.
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- W2284070931 date "1966-01-10" @default.
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- W2284070931 doi "https://doi.org/10.1002/macp.1966.020900112" @default.
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