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- W2284558413 abstract "Sluggish and narrow process window of phthalonitrile resin has tremendously limited their wide applications. In this work, a novel phthalonitrile containing benzoxazine (4,4′-(((propane-2,2-diylbis (2H-benzo [e] [1,3]oxazine-6,3 (4H)-diyl) bis(3,1-phenylene))bis(oxy)) diphthalonitrile, BA-ph) with ortho-diallyl bisphenol A (DABPA) was investigated. The processing window of the BA-ph/DABPA blends were found from 50°C to 185°C, which was significantly broader than that of the pure BA-ph (120–200°C). The composites were prepared through a curing process involving sequential polymerization of allyl moieties, ring-opening polymerization of oxazine rings and ring-forming polymerization of nitrile groups. BA-ph/DABPA/GF(glass fiber) composite laminates were prepared in this study, and the composite laminate with BA-ph/DABPA molar ratio of 2/2 showed an outstanding flexural strength and modulus of 560 MPa and 37 GPa, respectively, as well as a superior thermal and thermo-oxidative stability up to 408 and 410°C. These outstanding properties suggest that the BA-ph/DABPA/GF composites are suitable candidates as matrices for high performance composites. POLYM. ENG. SCI., 56:150–157, 2016. © 2015 Society of Plastics Engineers" @default.
- W2284558413 created "2016-06-24" @default.
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- W2284558413 date "2015-12-10" @default.
- W2284558413 modified "2023-10-16" @default.
- W2284558413 title "Effect of ortho-diallyl bisphenol A on the processability of phthalonitrile-based resin and their fiber-reinforced laminates" @default.
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- W2284558413 doi "https://doi.org/10.1002/pen.24237" @default.
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