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- W2284649099 abstract "Hot atoms, endowed with abnormally high energies much in excess of thermal equilibrium values, collide with molecules to produce chemical reactions not possible when the same chemical specles react with normal thermal energies. Such hot reactions: are temperature independent; may be eliminated by inert additives that remove the kinetic, vibrational or electronic energy of the excited species before it undergoes reactive collislons; and are not affected by low concentrations of reactive additives that serve as scavengers for thermalized free radicals. Previous observations indicate that the hot atom may form a new substance by replacing an atom or group and tsking its place in the original molecule in a single step process. Energy-transfer processes and some nuclear transformations which may produce hot atoms are included. The discussion is given in terms of hot-atom activation, and reactions in the gas, liquid, ad solid phases. (B.O.G.)" @default.
- W2284649099 created "2016-06-24" @default.
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- W2284649099 date "1961-10-01" @default.
- W2284649099 modified "2023-09-26" @default.
- W2284649099 title "RADIATION CHEMISTRY: HOT-ATOM REACTIONS" @default.
- W2284649099 hasPublicationYear "1961" @default.
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