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- W2284659462 abstract "The mechanism of energy transfer from Tb 3+ to Nd 3+ in glycerol:D 2 O solution at 280 K, 300 K and in its frozen glass at 80 K, 120 K, 190 K and 250 K has been examined. Analysis of the intensity and lifetime measurements of 5 D 4 level of Tb 3+ shows that at 280 K and 300 K in solution the transfer rate varies as the square of the Nd 3+ concentration. This suggests a dipole-dipole transfer in the glycerol:D 2 O solution. However, at lower temperatures up to 190 K, where the solution freezes into a glass, the dependence observed is linear at lower Nd 3+ concentrations and quadratic at higher concentrations. Moreover, the linear concentration dependence becomes more pronounced as the temperature of the glass is increased. This linear concentration dependence of the transfer rate and its temperature dependence have been ascribed to the migrational transfer accompanying the multipolar transfer. The coefficients of both the interactions at the above temperatures have been calculated." @default.
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- W2284659462 date "1978-05-01" @default.
- W2284659462 modified "2023-09-23" @default.
- W2284659462 title "Energy transfer from Tb 3+ to Nd 3+ in glycerol:D 2 O solution and frozen glass" @default.
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