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- W2284669685 abstract "The catalytic and enantioselective total synthesis of (−)-minovincine has been accomplished. The key highly substituted hydrocarbazole derivative was obtained by an asymmetric Diels–Alder reaction of siloxyvinylindole catalyzed by 0.5 mol % of a chiral holmium complex. The Diels–Alder adduct was converted to a tetracyclic intermediate in a one-pot procedure. No waste stereoisomers were produced throughout the entire total synthesis." @default.
- W2284669685 created "2016-06-24" @default.
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- W2284669685 date "2015-08-19" @default.
- W2284669685 modified "2023-10-16" @default.
- W2284669685 title "Chiral Holmium Complex-Catalyzed Synthesis of Hydrocarbazole from Siloxyvinylindole and Its Application to the Enantioselective Total Synthesis of (−)-Minovincine" @default.
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- W2284669685 doi "https://doi.org/10.1021/acs.joc.5b01393" @default.
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