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- W2284897115 abstract "We have designed a strategy for postsynthesis installation of the β-diketiminate (NacNac) functionality in a metal-organic framework (MOF) of UiO-topology. Metalation of the NacNac-MOF (I) with earth-abundant metal salts afforded the desired MOF-supported NacNac-M complexes (M = Fe, Cu, and Co) with coordination environments established by detailed EXAFS studies. The NacNac-Fe-MOF catalyst, I•Fe(Me), efficiently catalyzed the challenging intramolecular sp(3) C-H amination of a series of alkyl azides to afford α-substituted pyrrolidines. The NacNac-Cu-MOF catalyst, I•Cu(THF), was effective in promoting the intermolecular sp(3) C-H amination of cyclohexene using unprotected anilines to provide access to secondary amines in excellent selectivity. Finally, the NacNac-Co-MOF catalyst, I•Co(H), was used to catalyze alkene hydrogenation with turnover numbers (TONs) as high as 700,000. All of the NacNac-M-MOF catalysts were more effective than their analogous homogeneous catalysts and could be recycled and reused without a noticeable decrease in yield. The NacNac-MOFs thus provide a novel platform for engineering recyclable earth-abundant-element-based single-site solid catalysts for many important organic transformations." @default.
- W2284897115 created "2016-06-24" @default.
- W2284897115 creator A5007906338 @default.
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- W2284897115 creator A5074672389 @default.
- W2284897115 creator A5090217858 @default.
- W2284897115 date "2016-03-01" @default.
- W2284897115 modified "2023-09-27" @default.
- W2284897115 title "Robust and Porous β-Diketiminate-Functionalized Metal–Organic Frameworks for Earth-Abundant-Metal-Catalyzed C–H Amination and Hydrogenation" @default.
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- W2284897115 doi "https://doi.org/10.1021/jacs.5b13394" @default.
- W2284897115 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26885768" @default.
- W2284897115 hasPublicationYear "2016" @default.
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