Matches in SemOpenAlex for { <https://semopenalex.org/work/W2285183995> ?p ?o ?g. }
- W2285183995 endingPage "269" @default.
- W2285183995 startingPage "261" @default.
- W2285183995 abstract "A facile method to combine Keggin polyoxometalates (POMs) e.g. PMo12O403− (PMo12) and PW12O403− (PW12) in aqueous solutions has led to a unique electrochemical phenomenon, in which the POM mixtures demonstrate their own tunable redox activity, far different from the pure components. Through electrochemical and NMR analyses we have confirmed that this interesting behaviour arises from the spontaneous hydrolysis and recombination of PMo12 and PW12 ions forming complex blends of PMo12-xWx mixed addenda chemistries. While this process occurs spontaneously for the PMo12-PW12 system due to the ready hydrolysis, it can be induced in other POM mixtures such as SiMo12-SiW12 by adjusting the pH to stimulate hydrolysis. The highly tunable redox properties of the mixtures can be leveraged to design molecular coatings for a variety of applications. When deposited on nanocarbon, the overlapping redox features of the POM mixtures result in cyclic voltammograms with substantial pseudocapacitive currents which maintain relatively smooth charge/discharge profiles, ideal for supercapacitor electrodes." @default.
- W2285183995 created "2016-06-24" @default.
- W2285183995 creator A5010007968 @default.
- W2285183995 creator A5041413047 @default.
- W2285183995 creator A5087191593 @default.
- W2285183995 date "2016-05-01" @default.
- W2285183995 modified "2023-09-30" @default.
- W2285183995 title "The unique properties of aqueous polyoxometalate (POM) mixtures and their role in the design of molecular coatings for electrochemical energy storage" @default.
- W2285183995 cites W1582752573 @default.
- W2285183995 cites W1913589860 @default.
- W2285183995 cites W1976030641 @default.
- W2285183995 cites W1976175258 @default.
- W2285183995 cites W1978183136 @default.
- W2285183995 cites W1979915658 @default.
- W2285183995 cites W1981521137 @default.
- W2285183995 cites W1984520705 @default.
- W2285183995 cites W1988407594 @default.
- W2285183995 cites W1988443576 @default.
- W2285183995 cites W1993189322 @default.
- W2285183995 cites W1995648328 @default.
- W2285183995 cites W1997605401 @default.
- W2285183995 cites W2002443310 @default.
- W2285183995 cites W2005214635 @default.
- W2285183995 cites W2006705247 @default.
- W2285183995 cites W2008850296 @default.
- W2285183995 cites W2010615408 @default.
- W2285183995 cites W2013325159 @default.
- W2285183995 cites W2016262743 @default.
- W2285183995 cites W2024961207 @default.
- W2285183995 cites W2028490439 @default.
- W2285183995 cites W2035127456 @default.
- W2285183995 cites W2042161525 @default.
- W2285183995 cites W2049625113 @default.
- W2285183995 cites W2057034425 @default.
- W2285183995 cites W2057913872 @default.
- W2285183995 cites W2058112108 @default.
- W2285183995 cites W2058662424 @default.
- W2285183995 cites W2060132552 @default.
- W2285183995 cites W2066026992 @default.
- W2285183995 cites W2088401654 @default.
- W2285183995 cites W2095179230 @default.
- W2285183995 cites W2109973022 @default.
- W2285183995 cites W2132833523 @default.
- W2285183995 cites W2327172291 @default.
- W2285183995 cites W245876936 @default.
- W2285183995 cites W2951009225 @default.
- W2285183995 cites W2951533101 @default.
- W2285183995 cites W3214002072 @default.
- W2285183995 cites W656973856 @default.
- W2285183995 cites W973683596 @default.
- W2285183995 doi "https://doi.org/10.1016/j.electacta.2016.01.145" @default.
- W2285183995 hasPublicationYear "2016" @default.
- W2285183995 type Work @default.
- W2285183995 sameAs 2285183995 @default.
- W2285183995 citedByCount "34" @default.
- W2285183995 countsByYear W22851839952016 @default.
- W2285183995 countsByYear W22851839952017 @default.
- W2285183995 countsByYear W22851839952018 @default.
- W2285183995 countsByYear W22851839952019 @default.
- W2285183995 countsByYear W22851839952020 @default.
- W2285183995 countsByYear W22851839952021 @default.
- W2285183995 countsByYear W22851839952022 @default.
- W2285183995 countsByYear W22851839952023 @default.
- W2285183995 crossrefType "journal-article" @default.
- W2285183995 hasAuthorship W2285183995A5010007968 @default.
- W2285183995 hasAuthorship W2285183995A5041413047 @default.
- W2285183995 hasAuthorship W2285183995A5087191593 @default.
- W2285183995 hasConcept C127413603 @default.
- W2285183995 hasConcept C147789679 @default.
- W2285183995 hasConcept C161790260 @default.
- W2285183995 hasConcept C17525397 @default.
- W2285183995 hasConcept C178790620 @default.
- W2285183995 hasConcept C179104552 @default.
- W2285183995 hasConcept C184651966 @default.
- W2285183995 hasConcept C185592680 @default.
- W2285183995 hasConcept C192562407 @default.
- W2285183995 hasConcept C2777498215 @default.
- W2285183995 hasConcept C2993969710 @default.
- W2285183995 hasConcept C42360764 @default.
- W2285183995 hasConcept C52859227 @default.
- W2285183995 hasConcept C55904794 @default.
- W2285183995 hasConcept C6585489 @default.
- W2285183995 hasConcept C94412978 @default.
- W2285183995 hasConceptScore W2285183995C127413603 @default.
- W2285183995 hasConceptScore W2285183995C147789679 @default.
- W2285183995 hasConceptScore W2285183995C161790260 @default.
- W2285183995 hasConceptScore W2285183995C17525397 @default.
- W2285183995 hasConceptScore W2285183995C178790620 @default.
- W2285183995 hasConceptScore W2285183995C179104552 @default.
- W2285183995 hasConceptScore W2285183995C184651966 @default.
- W2285183995 hasConceptScore W2285183995C185592680 @default.
- W2285183995 hasConceptScore W2285183995C192562407 @default.
- W2285183995 hasConceptScore W2285183995C2777498215 @default.
- W2285183995 hasConceptScore W2285183995C2993969710 @default.
- W2285183995 hasConceptScore W2285183995C42360764 @default.
- W2285183995 hasConceptScore W2285183995C52859227 @default.
- W2285183995 hasConceptScore W2285183995C55904794 @default.
- W2285183995 hasConceptScore W2285183995C6585489 @default.