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• W2285244890 abstract "We report that the stereochemical outcome of the conjugate addition of organocopper reagents to bicyclic α,β-unsaturated lactams derived from pyroglutaminol is determined by the nature of the aminal group. Bicyclic α,β-unsaturated lactams in which the aminal is derived from a ketone have been found to afford products of syn conjugate addition. By contrast, bicyclic α,β-unsaturated lactams in which the aminal is derived from an aldehyde afford products of anti conjugate addition. These remarkably different results obtained from very similar starting materials are unexpected." @default.
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• W2285244890 date "2015-10-20" @default.
• W2285244890 modified "2023-10-10" @default.
• W2285244890 title "Reversal of Diastereoselection in the Conjugate Addition of Cuprates to Unsaturated Lactams" @default.
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• W2285244890 doi "https://doi.org/10.1021/acs.orglett.5b02533" @default.
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