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• W2286544553 abstract "We demonstrate that macromolecules in miscible polymer blends may behave as good, Theta, and poor polymeric solvents for each other. We construct a conceptual phase diagram, delineating the range of validity of the random-phase approximation, outside of which polymers contract or expand beyond their unperturbed dimensions, contrary to common assumptions. Remarkably, the correlation length for polymer blends, solutions, and supercritical mixtures collapses onto a master curve, reflecting universal behavior for macromolecules in polymeric and small-molecule Theta solvents." @default.
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• W2286544553 date "2002-06-19" @default.
• W2286544553 modified "2023-10-17" @default.
• W2286544553 title "Universal aspects of macromolecules in polymer blends, solutions, and supercritical mixtures" @default.
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• W2286544553 doi "https://doi.org/10.1103/physreve.65.061802" @default.
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