FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2286750867> ?p ?o ?g. }

• W2286750867 endingPage "5341" @default.
• W2286750867 startingPage "5335" @default.
• W2286750867 abstract "Native α-cyclodextrin- (α-CD) and permethylated α-CD (PMeCD)-based rotaxanes with various short alkylene chains as axles can be synthesized through a urea end-capping method. Native α-CD tends to form [3]- or [5]pseudorotaxanes and not [2]- or [4]pseudorotaxanes, which indicates that the coupled CDs act as a single fragment. End-capping reactions of the pseudorotaxanes with C18 and C24 axle lengths do not occur because the axle termini are covered by the densely stacked CDs. The number of PMeCDs on the pseudorotaxane is flexible and mainly depends on the axle length. Peracetylated α-CD (PAcCD)-based rotaxanes are synthesized through O-acetylation of the α-CD-based rotaxanes without any decomposition of the rotaxanated structures. The structures of PMeCD-based [3]- and [4]rotaxanes, and the molecular dynamics calculations on [3]pseudorotaxanes, indicate that the tail face of PMeCDs is regularly directed toward the axle termini. On the basis of the results obtained, it can be concluded that the directions and numbers of CDs in rotaxanes containing short alkylene chains depend on 1) the interactions between CDs, 2) the length of the alkylene axle, and 3) the interactions between the axle end and tail face of the CD." @default.
• W2286750867 created "2016-06-24" @default.
• W2286750867 creator A5022429673 @default.
• W2286750867 creator A5022766491 @default.
• W2286750867 creator A5046531978 @default.
• W2286750867 creator A5050453724 @default.
• W2286750867 creator A5063901413 @default.
• W2286750867 creator A5067261895 @default.
• W2286750867 creator A5080890475 @default.
• W2286750867 date "2016-02-23" @default.
• W2286750867 modified "2023-10-18" @default.
• W2286750867 title "Structural Analysis and Inclusion Mechanism of Native and Permethylated α-Cyclodextrin-Based Rotaxanes Containing Alkylene Axles" @default.
• W2286750867 cites W1965934688 @default.
• W2286750867 cites W1968417641 @default.
• W2286750867 cites W1971034600 @default.
• W2286750867 cites W1972520928 @default.
• W2286750867 cites W1972983249 @default.
• W2286750867 cites W1980108298 @default.
• W2286750867 cites W1980296408 @default.
• W2286750867 cites W1981581622 @default.
• W2286750867 cites W1983887990 @default.
• W2286750867 cites W1991262699 @default.
• W2286750867 cites W1991396361 @default.
• W2286750867 cites W1996481160 @default.
• W2286750867 cites W1997119204 @default.
• W2286750867 cites W1998800497 @default.
• W2286750867 cites W1999536406 @default.
• W2286750867 cites W2009068495 @default.
• W2286750867 cites W2009252241 @default.
• W2286750867 cites W2015224794 @default.
• W2286750867 cites W2021393358 @default.
• W2286750867 cites W2023046018 @default.
• W2286750867 cites W2023571831 @default.
• W2286750867 cites W2025668121 @default.
• W2286750867 cites W2036272964 @default.
• W2286750867 cites W2037378023 @default.
• W2286750867 cites W2038567328 @default.
• W2286750867 cites W2040413037 @default.
• W2286750867 cites W2044199573 @default.
• W2286750867 cites W2050619047 @default.
• W2286750867 cites W2053817846 @default.
• W2286750867 cites W2055977819 @default.
• W2286750867 cites W2062370453 @default.
• W2286750867 cites W2065245572 @default.
• W2286750867 cites W2067512012 @default.
• W2286750867 cites W2068170984 @default.
• W2286750867 cites W2069706601 @default.
• W2286750867 cites W2073024666 @default.
• W2286750867 cites W2077201072 @default.
• W2286750867 cites W2077375276 @default.
• W2286750867 cites W2078406406 @default.
• W2286750867 cites W2078859819 @default.
• W2286750867 cites W2078962868 @default.
• W2286750867 cites W2082069863 @default.
• W2286750867 cites W2083235345 @default.
• W2286750867 cites W2088880413 @default.
• W2286750867 cites W2103832312 @default.
• W2286750867 cites W2107110595 @default.
• W2286750867 cites W2116704965 @default.
• W2286750867 cites W2117040166 @default.
• W2286750867 cites W2117186599 @default.
• W2286750867 cites W2123741573 @default.
• W2286750867 cites W2129293411 @default.
• W2286750867 cites W2131740634 @default.
• W2286750867 cites W2132793059 @default.
• W2286750867 cites W2141324475 @default.
• W2286750867 cites W2143584463 @default.
• W2286750867 cites W2166064090 @default.
• W2286750867 cites W2166922054 @default.
• W2286750867 cites W2168465265 @default.
• W2286750867 cites W2313467375 @default.
• W2286750867 cites W2313958464 @default.
• W2286750867 cites W2314187652 @default.
• W2286750867 cites W2316137046 @default.
• W2286750867 cites W2316804147 @default.
• W2286750867 cites W2320865199 @default.
• W2286750867 cites W2321279662 @default.
• W2286750867 cites W2324805666 @default.
• W2286750867 cites W2331187108 @default.
• W2286750867 cites W2335724275 @default.
• W2286750867 cites W2342948144 @default.
• W2286750867 cites W4234992738 @default.
• W2286750867 cites W4246138457 @default.
• W2286750867 cites W4255517419 @default.
• W2286750867 doi "https://doi.org/10.1002/chem.201504882" @default.
• W2286750867 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26914705" @default.
• W2286750867 hasPublicationYear "2016" @default.
• W2286750867 type Work @default.
• W2286750867 sameAs 2286750867 @default.
• W2286750867 citedByCount "27" @default.
• W2286750867 countsByYear W22867508672016 @default.
• W2286750867 countsByYear W22867508672017 @default.
• W2286750867 countsByYear W22867508672018 @default.
• W2286750867 countsByYear W22867508672019 @default.
• W2286750867 countsByYear W22867508672020 @default.
• W2286750867 countsByYear W22867508672022 @default.
• W2286750867 countsByYear W22867508672023 @default.
• W2286750867 crossrefType "journal-article" @default.

• next