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- W2286810640 abstract "A cage cluster consisting of 31 uranyl and 9 Sm3+ polyhedra self-assembles in an alkaline aqueous peroxide solution and crystallizes (U31Sm9). Trimers of Sm3+ polyhedra are templated by μ3-η2:η2:η2-peroxide groups and link to oxo atoms of uranyl ions. Three such trimers link into a ring through uranyl hexagonal bipyramids, and these are attached through six polyhedra to a unit consisting of 21 uranyl hexagonal bipyramids to complete the cage. Luminescence spectra collected with an excitation wavelength of 420 nm reveal fine structure, which is not observed for a cluster containing only uranyl polyhedra." @default.
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- W2286810640 date "2016-02-29" @default.
- W2286810640 modified "2023-09-26" @default.
- W2286810640 title "Hybrid Lanthanide–Actinide Peroxide Cage Clusters" @default.
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- W2286810640 doi "https://doi.org/10.1021/acs.inorgchem.6b00207" @default.
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