FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2287175218> ?p ?o ?g. }

• W2287175218 endingPage "32" @default.
• W2287175218 startingPage "21" @default.
• W2287175218 abstract "Densities, ρ, speeds of sound, c, and refractive indices, nD, have been measured for the systems N,N-dimethylformamide (DMF) + propanone, +2-butanone, or +2-pentanone in the temperature range from (293.15 to 303.15) K and at T = 298.15 K for the DMF + 2-heptanone mixture. Due to the high volatility of acetone, the corresponding nD measurements were developed at T = (293.15 and 298.15) K. The direct experimental data were used to determine the excess molar volumes, VmE, and the excess refractive indices, nDE, at the working temperatures. Values of the excess functions at T = 298.15 K, for the speed of sound, cE, the isentropic compressibility, κSE and for the excess thermal expansion coefficient, αpE, were also calculated. The investigated systems are characterised by strong (amide + ketone) interactions, which become weaker when the alkanone size is increased. This is supported by negative VmE values; by the dependence on temperature and pressure of VmE, and by positive PintE (excess internal pressure) values. Analysis of the systems in terms of the Rao’s constant indicates that there is no complex formation. In addition, negative VmE values also reveal the existence of structural effects, which largely contribute to the excess molar enthalpy, HmE. VmE and HmE values increase with the chain length of the 2-alkanone. It allows conclude that the relative VmE variation with the ketone size is closely related to that of the interactional contribution to this excess function. Molar refraction values, Rm, show that dispersive interactions become more relevant for the systems including longer 2-alkanones." @default.
• W2287175218 created "2016-06-24" @default.
• W2287175218 creator A5006923274 @default.
• W2287175218 creator A5029774712 @default.
• W2287175218 creator A5062954999 @default.
• W2287175218 creator A5065622730 @default.
• W2287175218 creator A5067619915 @default.
• W2287175218 date "2016-07-01" @default.
• W2287175218 modified "2023-09-26" @default.
• W2287175218 title "Thermodynamics of amide+ketone mixtures. 1. Volumetric, speed of sound and refractive index data for N,N-dimethylformamide+2-alkanone systems at several temperatures" @default.
• W2287175218 cites W1591947373 @default.
• W2287175218 cites W1890777925 @default.
• W2287175218 cites W1966395375 @default.
• W2287175218 cites W1966451937 @default.
• W2287175218 cites W1967084753 @default.
• W2287175218 cites W1969861388 @default.
• W2287175218 cites W1974584151 @default.
• W2287175218 cites W1974690534 @default.
• W2287175218 cites W1975262077 @default.
• W2287175218 cites W1975379246 @default.
• W2287175218 cites W1977102210 @default.
• W2287175218 cites W1978367137 @default.
• W2287175218 cites W1982527023 @default.
• W2287175218 cites W1983279838 @default.
• W2287175218 cites W1984050510 @default.
• W2287175218 cites W1984214367 @default.
• W2287175218 cites W1984478637 @default.
• W2287175218 cites W1988054748 @default.
• W2287175218 cites W1988675314 @default.
• W2287175218 cites W1989087984 @default.
• W2287175218 cites W1991215536 @default.
• W2287175218 cites W1991650386 @default.
• W2287175218 cites W1991686393 @default.
• W2287175218 cites W1993222369 @default.
• W2287175218 cites W1994524981 @default.
• W2287175218 cites W1998329326 @default.
• W2287175218 cites W2000503596 @default.
• W2287175218 cites W2003519200 @default.
• W2287175218 cites W2003526020 @default.
• W2287175218 cites W2007479520 @default.
• W2287175218 cites W2008013850 @default.
• W2287175218 cites W2008779164 @default.
• W2287175218 cites W2009171075 @default.
• W2287175218 cites W2015061010 @default.
• W2287175218 cites W2018014775 @default.
• W2287175218 cites W2018830713 @default.
• W2287175218 cites W2019900847 @default.
• W2287175218 cites W2020222470 @default.
• W2287175218 cites W2021433216 @default.
• W2287175218 cites W2027224584 @default.
• W2287175218 cites W2028638270 @default.
• W2287175218 cites W2030384570 @default.
• W2287175218 cites W2032057129 @default.
• W2287175218 cites W2033157644 @default.
• W2287175218 cites W2033687514 @default.
• W2287175218 cites W2034175259 @default.
• W2287175218 cites W2037759633 @default.
• W2287175218 cites W2040565945 @default.
• W2287175218 cites W2040895426 @default.
• W2287175218 cites W2041232609 @default.
• W2287175218 cites W2043233420 @default.
• W2287175218 cites W2050866801 @default.
• W2287175218 cites W2055278654 @default.
• W2287175218 cites W2056638378 @default.
• W2287175218 cites W2057325863 @default.
• W2287175218 cites W2062132586 @default.
• W2287175218 cites W2062404774 @default.
• W2287175218 cites W2063563528 @default.
• W2287175218 cites W2064591792 @default.
• W2287175218 cites W2064900363 @default.
• W2287175218 cites W2069882545 @default.
• W2287175218 cites W2074211120 @default.
• W2287175218 cites W2074893553 @default.
• W2287175218 cites W2078409821 @default.
• W2287175218 cites W2082306037 @default.
• W2287175218 cites W2083047588 @default.
• W2287175218 cites W2085812047 @default.
• W2287175218 cites W2089034664 @default.
• W2287175218 cites W2089296155 @default.
• W2287175218 cites W2090596501 @default.
• W2287175218 cites W2090751051 @default.
• W2287175218 cites W2093399518 @default.
• W2287175218 cites W2093800602 @default.
• W2287175218 cites W2094163641 @default.
• W2287175218 cites W2107117912 @default.
• W2287175218 cites W211230692 @default.
• W2287175218 cites W2130169299 @default.
• W2287175218 cites W2153811572 @default.
• W2287175218 cites W2158174237 @default.
• W2287175218 cites W2171097175 @default.
• W2287175218 cites W2191484924 @default.
• W2287175218 cites W2207601599 @default.
• W2287175218 cites W2328762136 @default.
• W2287175218 cites W2952933621 @default.
• W2287175218 cites W3183786568 @default.
• W2287175218 cites W4210952926 @default.
• W2287175218 cites W4231065680 @default.
• W2287175218 cites W4231840857 @default.

• next