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- W2287236437 abstract "Near-phase-pure nanoparticle iron carbides (Fe3C and Fe5C2) were synthesised. Debye model calculations were used with hyperfineparameters gathered by 57Fe Mossbauer spectroscopy within a temperature range of 10 K to 293 K, with analysis providing Debye temperaturesof 422 K and 364 K for two Fe sites in Fe5C2 and 355 K for ferromagnetic Fe3C. The intrinsic isomer shifts were calculated as 0.45 mm s−1 and0.43 mm s−1 for iron sites 1 and 2 respectively in Fe5C2 and 0.42 mm s−1 for Fe3C. Recoil-free fractions for the two iron sites were also calculatedat f300 0.785 and 0.726 for site 1 and 2 respectively." @default.
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- W2287236437 date "2015-01-01" @default.
- W2287236437 modified "2023-10-01" @default.
- W2287236437 title "Variable Temperature 57Fe-Mössbauer Spectroscopy Study of Nanoparticle Iron Carbides" @default.
- W2287236437 doi "https://doi.org/10.5562/cca2782" @default.
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