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- W2287333717 abstract "A novel class of alkaline anion exchange membrane (AAEM) is presented, in the form of KOH-modified multilayer graphene oxide paper (GOKOH). Such membranes can be easily fabricated at large scale with varying thickness using conventional filtration techniques, and have high tensile strength (24.5 MPa). However, a large degree of swelling is observed. SEM investigations show that the morphology of GO changes after KOH-treatment, whilst XPS measurements and XRD analysis confirm successful chemical modification. The hydrogen gas permeability is several orders of magnitude lower than conventional polymer-based ionomer membranes. The maximum anion conductivity is 6.1 mS/cm at 70 °C, and the dominant charge carrier is confirmed to be OH− by utilization of anion and proton-conducting blocking layers. The ion exchange capacity is 6.1 mmol/g, measured by titration. A water-mediated reverse Grotthuss-like mechanism is proposed as the main diffusion mode of OH− ions. Finally, a prototype AAEM fuel cell is fabricated using a GOKOH membrane, confirming the applicability to real systems." @default.
- W2287333717 created "2016-06-24" @default.
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- W2287333717 date "2016-06-01" @default.
- W2287333717 modified "2023-10-18" @default.
- W2287333717 title "Alkaline anion exchange membranes based on KOH-treated multilayer graphene oxide" @default.
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- W2287333717 doi "https://doi.org/10.1016/j.memsci.2016.02.017" @default.
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