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- W2288049144 abstract "Th(' h('lix-coil t.ransition of ONA is treated in terms of a IlH)(('i in whiel! til(' hydrogen-Londing (and stacking) elH'rgy -1is atlaill('d 0111yif tite sC'gmellts carrying bases (A,T,G.C.) of eaeh strand make four rorr('ct tUfIlS to generate a half-helix. This modcl is equivall'llt to a Illodifipd Ising ehain with up to fourth nearest neighhor intf'factions alld highly biased statist.ical wcights. The average degree of 1H'licity fOlllpull'd for the Illodel can be fitt.ed weJl with the observed light-absorptioll data with an optimum choice of the ratio l = pI q of the correct turn prohability JI to the incoff('ct turn probahility q. The value of l is O.02as for s(''eral [)NA which show among the sharpest melting transions.leading to t.he fact that the t.urn prohahility p depends mainly on ti(' comrnOll hackbolle configllration carrying the bas('s. A relation is ohtailled among the melting tcmperature Tm, tile ratio l and the hond encrg.v A' ; 7'rr, = (In 0-1 A)kH. which indica tes that (a) the Illclling t('mperature 7.••.•varies linearl)' with the avcrage bond energy hand therefore tllf' G e pair contellt, and (b) the actual melt.ing t{'IIlp('rature TI(;l5TK) is r('duced b.••.thp factor -In t = 3.7.! from the bond telllperatllre 7b == h)kH( ' I:335/.). This r('lation also predicts the rise of the melting tcmperatufc 1'm with increasing salt collcentration, which tf'llds t.o make the helical [))';A more stable (higher J~-) (md make tite slrands more flexihle (higher t)." @default.
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- W2288049144 date "1988-01-01" @default.
- W2288049144 modified "2023-09-22" @default.
- W2288049144 title "Theory of the helix - coil transition of DNA based on the correlated walk model" @default.
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- W2288049144 hasPublicationYear "1988" @default.
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