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• W2288482011 abstract "Abstract Permeable mesoporous shells with a hollow interior are an important class of materials for the design and synthesis of nanoscale reactors and delivery vehicles. We started from Al‐based metal–organic framework MIL‐96(Al) nanocrystals, and herein we report a transformative method to prepare submicron reactors in which metal and metal oxide nanoparticles (NPs) are supported by γ‐Al 2 O 3 nanosheets and confined within a thin shell of mesoporous Al‐silicate (i.e., NPs/Al 2 O 3 @mAl‐silicate). As an example, such Pd/Al 2 O 3 @mAl‐silicate nanoreactors demonstrate a much higher catalytic stability than Pd protected within the hollow mAl‐silicate nanoshell and Pd supported on commercial Al 2 O 3 . As γ‐Al 2 O 3 is an important catalyst support, such robust catalyst devices promise broad applications in catalysis." @default.
• W2288482011 created "2016-06-24" @default.
• W2288482011 creator A5026686119 @default.
• W2288482011 creator A5066631060 @default.
• W2288482011 date "2016-03-03" @default.
• W2288482011 modified "2023-10-14" @default.
• W2288482011 title "Alumina-Supported Metal Catalysts inside a Mesoporous Aluminum-Silicate Shell: Nanoscale Reactors Prepared through the Transformation of MIL-96(Al) Nanocrystals" @default.
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• W2288482011 doi "https://doi.org/10.1002/cctc.201600062" @default.
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