Matches in SemOpenAlex for { <https://semopenalex.org/work/W2288827217> ?p ?o ?g. }
- W2288827217 endingPage "11687" @default.
- W2288827217 startingPage "11680" @default.
- W2288827217 abstract "A multistimuli response to temperature and pressure is found in the hybrid inorganic–organic perovskite-like [TPrA][Mn(dca)3] compound, which is related to a first-order structural phase transition near room temperature, Tt ≈ 330 K. This phase transition involves a transformation from room temperature polymorph I, with the noncentrosymmetric space group P4̅21c, to the high temperature polymorph II, with the centrosymmetric space group I4/mcm, and it implies ionic displacements, order–disorder phenomena, and a large and anisotropic thermal expansion (specially along the c-axis). As a consequence, [TPrA][Mn(dca)3] exhibits a dielectric anomaly, associated with the change from a cooperative to a noncooperative electric behavior (antiferroelectric (AFE)–paraelectric (PE) transition). The former implies an AFE distribution of electric dipoles in polymorph I, related to the described off-shift of the apolar TPrA cations and the order–disorder of the polar dca ligands mechanisms, that are different from those reported, up to now, for others perovskite-type hybrid compounds. Such cooperative electric order, below Tt ≈ 330 K, coexisting with long-range antiferromagnetic ordering below T = 2.1 K render the [TPrA][Mn(dca)3] a new type-I multiferroic material. In addition, the obtained experimental results reveal that this compound is also a multistimuli-responsive material, with a very large sensitivity toward temperature and applied external pressure, δTt/δP ≈ 24 K kbar–1, even for small values of pressure (P < 2 kbar). Therefore, this material opens up a potential interest for future technological applications, such as temperature/pressure sensing." @default.
- W2288827217 created "2016-06-24" @default.
- W2288827217 creator A5014968000 @default.
- W2288827217 creator A5016706327 @default.
- W2288827217 creator A5022215781 @default.
- W2288827217 creator A5027913198 @default.
- W2288827217 creator A5029472044 @default.
- W2288827217 creator A5032497191 @default.
- W2288827217 creator A5077709579 @default.
- W2288827217 creator A5085716031 @default.
- W2288827217 creator A5086313620 @default.
- W2288827217 date "2015-12-10" @default.
- W2288827217 modified "2023-10-18" @default.
- W2288827217 title "Role of Temperature and Pressure on the Multisensitive Multiferroic Dicyanamide Framework [TPrA][Mn(dca)<sub>3</sub>] with Perovskite-like Structure" @default.
- W2288827217 cites W149469744 @default.
- W2288827217 cites W1895463043 @default.
- W2288827217 cites W1966535971 @default.
- W2288827217 cites W1978514978 @default.
- W2288827217 cites W1990170643 @default.
- W2288827217 cites W1998132802 @default.
- W2288827217 cites W2003989622 @default.
- W2288827217 cites W2007045586 @default.
- W2288827217 cites W2011372511 @default.
- W2288827217 cites W2031611838 @default.
- W2288827217 cites W2048518241 @default.
- W2288827217 cites W2051619086 @default.
- W2288827217 cites W2059233014 @default.
- W2288827217 cites W2059841912 @default.
- W2288827217 cites W2063871837 @default.
- W2288827217 cites W2068282876 @default.
- W2288827217 cites W2073573363 @default.
- W2288827217 cites W2080874354 @default.
- W2288827217 cites W2083242163 @default.
- W2288827217 cites W2083833353 @default.
- W2288827217 cites W2089556499 @default.
- W2288827217 cites W2092911179 @default.
- W2288827217 cites W2108219971 @default.
- W2288827217 cites W2117320601 @default.
- W2288827217 cites W2117808443 @default.
- W2288827217 cites W2122179865 @default.
- W2288827217 cites W2122349947 @default.
- W2288827217 cites W2124066315 @default.
- W2288827217 cites W2131350133 @default.
- W2288827217 cites W2132216432 @default.
- W2288827217 cites W2147673995 @default.
- W2288827217 cites W2155176366 @default.
- W2288827217 cites W2163414349 @default.
- W2288827217 cites W2165576546 @default.
- W2288827217 cites W2313570818 @default.
- W2288827217 cites W2322774855 @default.
- W2288827217 cites W2331208638 @default.
- W2288827217 cites W2334711186 @default.
- W2288827217 cites W2952089022 @default.
- W2288827217 cites W3100164847 @default.
- W2288827217 cites W4232665156 @default.
- W2288827217 cites W4242023898 @default.
- W2288827217 doi "https://doi.org/10.1021/acs.inorgchem.5b01652" @default.
- W2288827217 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26652059" @default.
- W2288827217 hasPublicationYear "2015" @default.
- W2288827217 type Work @default.
- W2288827217 sameAs 2288827217 @default.
- W2288827217 citedByCount "70" @default.
- W2288827217 countsByYear W22888272172016 @default.
- W2288827217 countsByYear W22888272172017 @default.
- W2288827217 countsByYear W22888272172018 @default.
- W2288827217 countsByYear W22888272172019 @default.
- W2288827217 countsByYear W22888272172020 @default.
- W2288827217 countsByYear W22888272172021 @default.
- W2288827217 countsByYear W22888272172022 @default.
- W2288827217 countsByYear W22888272172023 @default.
- W2288827217 crossrefType "journal-article" @default.
- W2288827217 hasAuthorship W2288827217A5014968000 @default.
- W2288827217 hasAuthorship W2288827217A5016706327 @default.
- W2288827217 hasAuthorship W2288827217A5022215781 @default.
- W2288827217 hasAuthorship W2288827217A5027913198 @default.
- W2288827217 hasAuthorship W2288827217A5029472044 @default.
- W2288827217 hasAuthorship W2288827217A5032497191 @default.
- W2288827217 hasAuthorship W2288827217A5077709579 @default.
- W2288827217 hasAuthorship W2288827217A5085716031 @default.
- W2288827217 hasAuthorship W2288827217A5086313620 @default.
- W2288827217 hasConcept C121332964 @default.
- W2288827217 hasConcept C123266903 @default.
- W2288827217 hasConcept C133386390 @default.
- W2288827217 hasConcept C149288129 @default.
- W2288827217 hasConcept C154881586 @default.
- W2288827217 hasConcept C155011858 @default.
- W2288827217 hasConcept C155355069 @default.
- W2288827217 hasConcept C161790260 @default.
- W2288827217 hasConcept C178790620 @default.
- W2288827217 hasConcept C185592680 @default.
- W2288827217 hasConcept C192562407 @default.
- W2288827217 hasConcept C26873012 @default.
- W2288827217 hasConcept C2776693317 @default.
- W2288827217 hasConcept C49040817 @default.
- W2288827217 hasConcept C79090758 @default.
- W2288827217 hasConcept C8010536 @default.
- W2288827217 hasConceptScore W2288827217C121332964 @default.
- W2288827217 hasConceptScore W2288827217C123266903 @default.