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- W2289204516 abstract "Two new Ru(II) complexes containing guanidinium groups have been synthesized, characterized and analyzed according to their interactions with different G-quadruplexes and duplex DNA. A FRET assay and a competitive FRET assay showed that both complexes promote the formation and stabilization of the human telomeric (h-telo) G-quadruplex and exhibit higher selectivity compared to promoters (such as c-myc, c-kit and bcl2) or duplex DNA. After binding to G-quadruplex, the two complexes have shown different DNA affinity and fluorescence enhancement. CD analyses further indicate that the two complexes display the ability to induce and stabilize the formation of antiparallel G-quadruplex structures in K+, Na+ or ion-free buffers. The binding stoichiometry with h-telo was of the order of three ruthenium complexes per quadruplex." @default.
- W2289204516 created "2016-06-24" @default.
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- W2289204516 date "2016-05-01" @default.
- W2289204516 modified "2023-09-27" @default.
- W2289204516 title "Synthesis, characterization and DNA binding studies of two Ru(II) complexes containing guanidinium ligands" @default.
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- W2289204516 doi "https://doi.org/10.1016/j.poly.2016.02.038" @default.
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