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• W2289224768 startingPage "2435" @default.
• W2289224768 abstract "Designed catalyst poisons can be deliberately added in various reactions for tuning chemoselectivity. In general, the poisons are “transient” selectivity modifiers that are readily leached out during reactions and thus should be continuously fed to maintain the selectivity. In this work, we supported Pd catalysts on a thermochemically stable cross-linked polymer containing diphenyl sulfide linkages, which can simultaneously act as a catalyst support and a “permanent” selectivity modifier. The entire surfaces of the Pd clusters were ligated (or poisoned) by sulfide groups of the polymer support. The sulfide groups capping the Pd surface behaved like a “molecular gate” that enabled exceptionally discriminative adsorption of alkynes over alkenes. H2/D2 isotope exchange revealed that the capped Pd surface alone is inactive for H2 (or D2) dissociation, but in the presence of coflowing acetylene (alkyne), it becomes active for H2 dissociation as well as acetylene hydrogenation. The results indicated that acetyl..." @default.
• W2289224768 created "2016-06-24" @default.
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• W2289224768 date "2016-03-10" @default.
• W2289224768 modified "2023-10-13" @default.
• W2289224768 title "Cross-Linked “Poisonous” Polymer: Thermochemically Stable Catalyst Support for Tuning Chemoselectivity" @default.
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• W2289224768 doi "https://doi.org/10.1021/acscatal.5b02613" @default.
• W2289224768 hasPublicationYear "2016" @default.
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