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- W2289322528 abstract "A stereoselective synthesis of decahydrofuro[3,2-d]isochromene derivatives has been achieved by the condensation of 2-cyclohexenylbutane-1,4-diol with aldehydes in the presence of a stochiometric amount of BF3·OEt2 in dichloromethane at −78 °C. Similarly, the condensation of 2-cyclopentenylbutan-1,4-diol with aldehydes provides the corresponding octahydro-2H-cyclopenta[c]furo[2,3-d]pyran derivatives in good yields with high diastereoselectivity. It is an elegant strategy for the quick construction of tricyclic architectures with four contiguous stereogenic centers in a single step. These tricyclic frameworks are the integral part of numerous natural products." @default.
- W2289322528 created "2016-06-24" @default.
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- W2289322528 date "2015-11-20" @default.
- W2289322528 modified "2023-10-16" @default.
- W2289322528 title "Domino Strategy for the Stereoselective Construction of Angularly Fused Tricyclic Ethers" @default.
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- W2289322528 doi "https://doi.org/10.1021/acs.joc.5b02241" @default.
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