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- W2289409660 endingPage "2747" @default.
- W2289409660 startingPage "2737" @default.
- W2289409660 abstract "The synthesis, structure, and complete characterization of mono- and bimetallic dyads joining Fischer carbene complexes and BODIPY chromophores are reported. In these organometallic species, the Fischer carbene complex is attached to the BODIPY moiety through a p-aminophenyl group linked at the C8 carbon atom of the BODIPY core. The photophysical properties, namely the corresponding UV/vis absorption and emission spectra of these new metal-carbene complexes, are analyzed and discussed. It is found that whereas the absorption of the considered dyads strongly resembles that of the parent 4-anilinyl-substituted BODIPY, the fluorescence emission is significantly reduced in these species, very likely as a result of a Förster-type energy transfer mechanism. At variance, the replacement of the pentacarbonyl-metal(0) fragment by a carbonyl group leads to high fluorescence emission intensity. In addition, the emissive properties of the BODIPY core in these organometallic dyads can be tuned by remote groups by means of π-conjugation, as supported by density functional theory calculations." @default.
- W2289409660 created "2016-06-24" @default.
- W2289409660 creator A5009883474 @default.
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- W2289409660 creator A5055664592 @default.
- W2289409660 date "2016-03-03" @default.
- W2289409660 modified "2023-10-17" @default.
- W2289409660 title "Remote Control by π-Conjugation of the Emissive Properties of Fischer Carbene-BODIPY Dyads" @default.
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- W2289409660 doi "https://doi.org/10.1021/acs.inorgchem.5b02448" @default.
- W2289409660 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26938956" @default.
- W2289409660 hasPublicationYear "2016" @default.
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