Matches in SemOpenAlex for { <https://semopenalex.org/work/W2289484296> ?p ?o ?g. }
- W2289484296 endingPage "2542" @default.
- W2289484296 startingPage "2534" @default.
- W2289484296 abstract "Tributyrin, the triglyceride ester, exhibits strong properties as inhibitor of cancer cell growth in both humans and animals, which can increase the shelf life of drug. In this paper, tributyrin was synthesized by esterification reaction of butanoic acid with glycerol catalyzed by a low cost, ecofriendly green catalyst sulfated iron oxide. Effect of varying catalyst loading, stirring speed, and temperature on initial reaction rate was investigated. Reaction kinetics and adsorption and thermodynamic parameters were determined by evaluating the effect of concentration of butanoic acid, glycerol, and water addition on reaction rate. Eley–Rideal model using activity coefficients was employed to account for nonideality of the system to elucidate the experimental data. A maximal acid conversion of 91.8% was obtained at the temperature of 448.15 K. Activation energy was calculated to be 25.348 kJ/mol. The end product of reaction was characterized by means of thin layer chromatography (TLC), Fourier transform infrared spectroscopy (FT-IR), and gas chromatography with mass spectrometry (GC–MS). The formation of mono-, di-, and tributyrin with the selectivity of 2.12%, 2.08%, and 77.9% at the optimum reaction conditions was verified. Thus, a reaction mechanism on catalyst surface was revealed to describe the apparent reaction pathway to illustrate the formation of reaction products. This research work will pave ways for the improvement in the shelf life of drug in the treatment of cancer." @default.
- W2289484296 created "2016-06-24" @default.
- W2289484296 creator A5031817281 @default.
- W2289484296 creator A5050113008 @default.
- W2289484296 creator A5070141310 @default.
- W2289484296 date "2016-02-29" @default.
- W2289484296 modified "2023-09-25" @default.
- W2289484296 title "Facile Synthesis of Tributyrin Catalyzed by Versatile Sulfated Iron Oxide: Reaction Pathway and Kinetic Evaluation" @default.
- W2289484296 cites W1531931873 @default.
- W2289484296 cites W1963694167 @default.
- W2289484296 cites W1964740218 @default.
- W2289484296 cites W1974051449 @default.
- W2289484296 cites W1975788716 @default.
- W2289484296 cites W1975944613 @default.
- W2289484296 cites W1976883040 @default.
- W2289484296 cites W1993004249 @default.
- W2289484296 cites W2003434502 @default.
- W2289484296 cites W2021684732 @default.
- W2289484296 cites W2026072727 @default.
- W2289484296 cites W2039293215 @default.
- W2289484296 cites W2040066342 @default.
- W2289484296 cites W2040856544 @default.
- W2289484296 cites W2041975116 @default.
- W2289484296 cites W2047408717 @default.
- W2289484296 cites W2048333795 @default.
- W2289484296 cites W2052836851 @default.
- W2289484296 cites W2054781839 @default.
- W2289484296 cites W2054844022 @default.
- W2289484296 cites W2058304276 @default.
- W2289484296 cites W2058851494 @default.
- W2289484296 cites W2060977059 @default.
- W2289484296 cites W2063336001 @default.
- W2289484296 cites W2065966415 @default.
- W2289484296 cites W2067060500 @default.
- W2289484296 cites W2075132966 @default.
- W2289484296 cites W2077823671 @default.
- W2289484296 cites W2081455172 @default.
- W2289484296 cites W2083599327 @default.
- W2289484296 cites W2110817382 @default.
- W2289484296 cites W2142488399 @default.
- W2289484296 cites W2150962987 @default.
- W2289484296 cites W2152190937 @default.
- W2289484296 cites W2157528067 @default.
- W2289484296 cites W2168520542 @default.
- W2289484296 cites W2318353003 @default.
- W2289484296 cites W2323416136 @default.
- W2289484296 cites W2324599359 @default.
- W2289484296 cites W2562432519 @default.
- W2289484296 cites W288830614 @default.
- W2289484296 cites W3150017537 @default.
- W2289484296 cites W4241882250 @default.
- W2289484296 doi "https://doi.org/10.1021/acs.iecr.5b04294" @default.
- W2289484296 hasPublicationYear "2016" @default.
- W2289484296 type Work @default.
- W2289484296 sameAs 2289484296 @default.
- W2289484296 citedByCount "8" @default.
- W2289484296 countsByYear W22894842962016 @default.
- W2289484296 countsByYear W22894842962017 @default.
- W2289484296 countsByYear W22894842962018 @default.
- W2289484296 countsByYear W22894842962019 @default.
- W2289484296 countsByYear W22894842962021 @default.
- W2289484296 crossrefType "journal-article" @default.
- W2289484296 hasAuthorship W2289484296A5031817281 @default.
- W2289484296 hasAuthorship W2289484296A5050113008 @default.
- W2289484296 hasAuthorship W2289484296A5070141310 @default.
- W2289484296 hasConcept C127413603 @default.
- W2289484296 hasConcept C150394285 @default.
- W2289484296 hasConcept C161790260 @default.
- W2289484296 hasConcept C162356407 @default.
- W2289484296 hasConcept C175113610 @default.
- W2289484296 hasConcept C178790620 @default.
- W2289484296 hasConcept C179104552 @default.
- W2289484296 hasConcept C181199279 @default.
- W2289484296 hasConcept C185592680 @default.
- W2289484296 hasConcept C2778855143 @default.
- W2289484296 hasConcept C2779697368 @default.
- W2289484296 hasConcept C2780881558 @default.
- W2289484296 hasConcept C42360764 @default.
- W2289484296 hasConcept C43617362 @default.
- W2289484296 hasConcept C95121573 @default.
- W2289484296 hasConceptScore W2289484296C127413603 @default.
- W2289484296 hasConceptScore W2289484296C150394285 @default.
- W2289484296 hasConceptScore W2289484296C161790260 @default.
- W2289484296 hasConceptScore W2289484296C162356407 @default.
- W2289484296 hasConceptScore W2289484296C175113610 @default.
- W2289484296 hasConceptScore W2289484296C178790620 @default.
- W2289484296 hasConceptScore W2289484296C179104552 @default.
- W2289484296 hasConceptScore W2289484296C181199279 @default.
- W2289484296 hasConceptScore W2289484296C185592680 @default.
- W2289484296 hasConceptScore W2289484296C2778855143 @default.
- W2289484296 hasConceptScore W2289484296C2779697368 @default.
- W2289484296 hasConceptScore W2289484296C2780881558 @default.
- W2289484296 hasConceptScore W2289484296C42360764 @default.
- W2289484296 hasConceptScore W2289484296C43617362 @default.
- W2289484296 hasConceptScore W2289484296C95121573 @default.
- W2289484296 hasFunder F4320320767 @default.
- W2289484296 hasIssue "9" @default.
- W2289484296 hasLocation W22894842961 @default.