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- W2289687688 abstract "A variety of chemical systems have been developed to separate trivalent actinides from lanthanides that depend on the slightly stronger complexes formed by the trivalent actinides with ligands such as chloride or diethylenetriaminepentraacetic acid. The greater stability of the actinide complexes in these systems has been attributed to a slightly greater covalent bonding component for the actinide ions relative to the lanthanide ions. The authors have developed extraction systems that use ligands with combinations of oxygen, nitrogen, or sulfur donor atoms that achieve a good group separation of the trivalent actinides and lanthanides. Such systems could find application in advanced partitioning schemes for nuclear waste. The behavior of the extraction systems and structural data from actinide complexes of the ligands are consistent with the hypothesis of a slightly greater covalent bonding component for the actinides." @default.
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- W2289687688 date "1993-12-31" @default.
- W2289687688 modified "2023-09-27" @default.
- W2289687688 title "Separation of trivalent actinides and lanthanides" @default.
- W2289687688 hasPublicationYear "1993" @default.
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