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- W2290184511 abstract "Dicobalt octacarbonyl-catalyzed carbonylative cyclization of pyridinyl diazoacetates is developed for the synthesis of pyridoisoquinolinones under mild conditions (room temperature) in a carbon monoxide atmosphere. Moreover, a synthetic method for various pyridoisoquinolinones from ethylpyridinyl aryl acetates is demonstrated through diazotization using TsN3 and DBU followed by Co-catalyzed carbonylation to generate ketene intermediates, which can subsequently undergo intramolecular cyclization under mild conditions in a carbon monoxide atmosphere in a semi-one-pot fashion." @default.
- W2290184511 created "2016-06-24" @default.
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- W2290184511 date "2015-12-14" @default.
- W2290184511 modified "2023-10-12" @default.
- W2290184511 title "Cobalt-Catalyzed Carbonylative Cyclization of Pyridinyl Diazoacetates for the Synthesis of Pyridoisoquinolinones" @default.
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- W2290184511 doi "https://doi.org/10.1021/acs.orglett.5b03340" @default.
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- W2290184511 hasPublicationYear "2015" @default.
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