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- W2290260603 abstract "Abstract ZrB 2 –Al 2 O 3 in situ composite powders were synthesized at 1550 °C via a novel solid-state precursor route using ZrO 2 , Al, and BN as raw materials. The final ZrB 2 –Al 2 O 3 composite powders, consisting of large crystal Al 2 O 3 particles (several micrometers) and fine ZrB 2 particles (100–400 nm), form an interwoven network and are intimately mixed on a microscopic scale. The formation mechanism for ZrB 2 –Al 2 O 3 composite powders comprises two steps: aluminothermic reduction of ZrO 2 , which generates Zr–Al alloy compounds and the coproducts Al 2 O 3 , then followed by a series of solid reactions between Zr and BN to give the ZrB, ZrN, and ZrB 2 products. The aluminothermic reduction is a fast reaction, while the reaction between Zr and BN to obtain the final ZrB 2 product is the limiting step in the conversion process of the precursor powders." @default.
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- W2290260603 date "2016-03-01" @default.
- W2290260603 modified "2023-09-26" @default.
- W2290260603 title "Synthesis and formation mechanism of ZrB2–Al2O3 composite powder starting from ZrO2, Al, and BN" @default.
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- W2290260603 doi "https://doi.org/10.1016/j.apt.2016.02.030" @default.
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