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- W2291014769 abstract "The reaction of sodium hydro‐tris(phenylthioimidazolyl)borate (NaTm Ph ) with silicon tetraiodide gives rise to the first crystallographically characterised molecular silicon compounds, [Si(Tm Ph ) 2 ] 2X (X = I – and I 3 – ), in which the silicon is found in a regular S 6 environment. The [Si(Tm Ph ) 2 ] 2+ cation is subjected to analysis using DFT methods to explain why an S 6 coordination motif is preferred to an S 4 coordination motif." @default.
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- W2291014769 date "2016-03-01" @default.
- W2291014769 modified "2023-10-17" @default.
- W2291014769 title "The First Structurally Characterised Example of Silicon in an S6 Coordination Sphere" @default.
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- W2291014769 doi "https://doi.org/10.1002/ejic.201501269" @default.
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