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• W2291050092 abstract "A general, parallel, and collective synthesis of 5/5/5- and 5/5/6-ring fusion topologies of tricyclic spiranoid lactones through the controlled cyclizations of easily accessible, common key precursors is described. The rapid composition of key cycloalkyl methylene precursors yielded an assembly of bicyclic diastereoisomeric iodolactones, which were individually converted into a wide range of tricyclic, angularly fused spiranoid lactones in a regioselective and stereodirected fashion through the diastereoisomeric differentiation of a collective key precursor. The critical stereochemical assignment of the bicyclic starting materials, as well as the tricyclic targets, was confirmed by X-ray crystal structure determination." @default.
• W2291050092 created "2016-06-24" @default.
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• W2291050092 date "2016-01-11" @default.
• W2291050092 modified "2023-09-27" @default.
• W2291050092 title "Stereo- and Regioselective Synthesis of Tricyclic Spirolactones by Diastereoisomeric Differentiation of a Collective Key Precursor" @default.
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• W2291050092 doi "https://doi.org/10.1002/chem.201504310" @default.
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