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- W2291338052 abstract "As an eco-friendly polymer with tremendous potential to replace traditional petroleum-based and nonbiodegradable polymers, the current use of poly(l-lactide) (PLLA) in large-scale commercial applications still faces some barriers mostly associated with its inherent brittleness and poor heat resistance. In this work, we propose a novel and facile strategy to simultaneously address these obstacles by introducing small amounts of poly(d-lactide) (PDLA) into thermoplastic polyurethane (TPU) toughened PLLA blends through melt-blending. The results manifest that the introduced PDLA chains can readily interact with PLLA matrix chains and rapidly cocrystallize into stereocomplex (sc) crystallites capable of acting as an efficient rheology modifier to dramatically improve melt viscoelasticity of the PLLA matrix and subsequently induce the morphological change of the dispersed TPU phase from a typical sea–island structure to a unique networklike structure, thus endowing PLLA/TPU/PDLA blends with remarkably improved..." @default.
- W2291338052 created "2016-06-24" @default.
- W2291338052 creator A5006219407 @default.
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- W2291338052 date "2015-11-30" @default.
- W2291338052 modified "2023-10-12" @default.
- W2291338052 title "Remarkably Enhanced Impact Toughness and Heat Resistance of poly(<scp>l</scp>-Lactide)/Thermoplastic Polyurethane Blends by Constructing Stereocomplex Crystallites in the Matrix" @default.
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- W2291338052 doi "https://doi.org/10.1021/acssuschemeng.5b00816" @default.
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