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• W2291444549 endingPage "578" @default.
• W2291444549 startingPage "565" @default.
• W2291444549 abstract "Indium and nitrogen codoping in ZnO leads to a solid solution of InN in ZnO with a composition of (Zn1−zInz)(O1−xNx). A simple solution combustion method has been adopted to prepare the above materials in less than 10 min with metal nitrates as the metal ion source and urea as fuel. With reference to ZnO, significant increase in lattice parameters was observed with increasing In-content. However, the In2O3 phase was observed along with InN for In content ≥10%. Optical absorption extended into the visible region, at least up to 550 nm, demonstrates an effective reduction of optical band gap due to the formation of solid solution. A new feature observed just above O 2p valence band in X-ray photoelectron spectroscopy (XPS) suggests the creation of N 2p states from InN; the N 1s core level XPS result too confirms nitride contribution. Raman spectroscopy and secondary ion mass spectrometry results show direct In−N, Zn−N, and In−N−Zn fragments in (Zn1−zInz)(O1−xNx). Catalytic activity explored for oxidation of 2-butanol to ethyl methyl ketone demonstrates a high selectivity at 350 and 400 °C. All of the above characteristics suggest the multifunctional nature of (Zn1−zInz)(O1−xNx) and its potential for other applications." @default.
• W2291444549 created "2016-06-24" @default.
• W2291444549 creator A5006444762 @default.
• W2291444549 creator A5018323236 @default.
• W2291444549 creator A5022117066 @default.
• W2291444549 creator A5030363496 @default.
• W2291444549 creator A5037665898 @default.
• W2291444549 creator A5063566903 @default.
• W2291444549 creator A5083876599 @default.
• W2291444549 date "2009-12-17" @default.
• W2291444549 modified "2023-10-16" @default.
• W2291444549 title "Structure, Electronic Structure, Optical, and Dehydrogenation Catalytic Study of (Zn_1−<i>z</i>In_<i>z</i>)(O_1−<i>x</i>N_<i>x</i>) Solid Solution" @default.
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