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• W2291455828 abstract "Homoleptic fac-IrIIIL3 complexes of 5-aryl-4H-1,2,4-triazole ligands are sky blue emitters. When unsymmetrically substituted, the triazole ligands exhibit atropisomerism, and upon cyclometalation to Ir(III) a mixture of diastereomers is formed. We have isolated and structurally characterized all four possible diastereomers of the fac-IrIIIL3 complex formed upon cyclometalation of an atropisomeric 5-aryl-4H-1,2,4-triazole ligand onto Ir(III). The phosphorescent blue emitting materials reported herein are among the most efficient to date, with quantum efficiencies above 95%." @default.
• W2291455828 created "2016-06-24" @default.
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• W2291455828 date "2015-05-10" @default.
• W2291455828 modified "2023-10-14" @default.
• W2291455828 title "Highly Quantum Efficient Phosphorescent Sky Blue Emitters Based on Diastereomeric Iridium(III) Complexes of Atropisomeric 5-Aryl-4<i>H</i>-1,2,4-triazole Ligands" @default.
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• W2291455828 doi "https://doi.org/10.1021/acs.organomet.5b00198" @default.
• W2291455828 hasPublicationYear "2015" @default.
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