Matches in SemOpenAlex for { <https://semopenalex.org/work/W2291495588> ?p ?o ?g. }
- W2291495588 endingPage "6541" @default.
- W2291495588 startingPage "6537" @default.
- W2291495588 abstract "The concomitant activation of carbonyl substrates by two Lewis acids has been investigated by using [1,2-(Ph2MeSb)2C6H4]2+ ([1]2+), an antimony-based bidentate Lewis acid obtained by methylation of the corresponding distibine. Unlike the simple stibonium cation [Ph3MeSb]+, dication [1]2+ efficiently catalyzes the hydrosilylation of benzaldehyde under mild conditions. The catalytic activity of this dication is correlated to its ability to doubly activate the carbonyl functionality of the organic substrate. This view is supported by the isolation of [1-μ2-DMF][OTf]2, an adduct, in which the DMF oxygen atom bridges the two antimony centers." @default.
- W2291495588 created "2016-06-24" @default.
- W2291495588 creator A5030026591 @default.
- W2291495588 creator A5038733654 @default.
- W2291495588 creator A5068820252 @default.
- W2291495588 date "2016-03-16" @default.
- W2291495588 modified "2023-10-01" @default.
- W2291495588 title "Promoting the Hydrosilylation of Benzaldehyde by Using a Dicationic Antimony‐Based Lewis Acid: Evidence for the Double Electrophilic Activation of the Carbonyl Substrate" @default.
- W2291495588 cites W1481764835 @default.
- W2291495588 cites W1484350064 @default.
- W2291495588 cites W1964885234 @default.
- W2291495588 cites W1967621311 @default.
- W2291495588 cites W1967663220 @default.
- W2291495588 cites W1997554796 @default.
- W2291495588 cites W1998704778 @default.
- W2291495588 cites W1998965830 @default.
- W2291495588 cites W1999145802 @default.
- W2291495588 cites W2004513099 @default.
- W2291495588 cites W2014200671 @default.
- W2291495588 cites W2025601291 @default.
- W2291495588 cites W2025957746 @default.
- W2291495588 cites W2034151368 @default.
- W2291495588 cites W2038767330 @default.
- W2291495588 cites W2044378109 @default.
- W2291495588 cites W2049913248 @default.
- W2291495588 cites W2050890677 @default.
- W2291495588 cites W2053642303 @default.
- W2291495588 cites W2057055628 @default.
- W2291495588 cites W2060267686 @default.
- W2291495588 cites W2068191591 @default.
- W2291495588 cites W2076730615 @default.
- W2291495588 cites W2086817741 @default.
- W2291495588 cites W2093939830 @default.
- W2291495588 cites W2112584350 @default.
- W2291495588 cites W2131172140 @default.
- W2291495588 cites W2133830955 @default.
- W2291495588 cites W2134989607 @default.
- W2291495588 cites W2141359487 @default.
- W2291495588 cites W2142905014 @default.
- W2291495588 cites W2146817037 @default.
- W2291495588 cites W2159735628 @default.
- W2291495588 cites W2167330720 @default.
- W2291495588 cites W2312517576 @default.
- W2291495588 cites W2315752527 @default.
- W2291495588 cites W2318085588 @default.
- W2291495588 cites W2319298142 @default.
- W2291495588 cites W2325374786 @default.
- W2291495588 cites W2328890485 @default.
- W2291495588 cites W2335705928 @default.
- W2291495588 cites W2615871312 @default.
- W2291495588 cites W2952024323 @default.
- W2291495588 cites W4244240749 @default.
- W2291495588 cites W4247615205 @default.
- W2291495588 cites W4256475378 @default.
- W2291495588 cites W599554044 @default.
- W2291495588 cites W78337159 @default.
- W2291495588 doi "https://doi.org/10.1002/chem.201600971" @default.
- W2291495588 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26934491" @default.
- W2291495588 hasPublicationYear "2016" @default.
- W2291495588 type Work @default.
- W2291495588 sameAs 2291495588 @default.
- W2291495588 citedByCount "69" @default.
- W2291495588 countsByYear W22914955882016 @default.
- W2291495588 countsByYear W22914955882017 @default.
- W2291495588 countsByYear W22914955882018 @default.
- W2291495588 countsByYear W22914955882019 @default.
- W2291495588 countsByYear W22914955882020 @default.
- W2291495588 countsByYear W22914955882021 @default.
- W2291495588 countsByYear W22914955882022 @default.
- W2291495588 countsByYear W22914955882023 @default.
- W2291495588 crossrefType "journal-article" @default.
- W2291495588 hasAuthorship W2291495588A5030026591 @default.
- W2291495588 hasAuthorship W2291495588A5038733654 @default.
- W2291495588 hasAuthorship W2291495588A5068820252 @default.
- W2291495588 hasConcept C108204754 @default.
- W2291495588 hasConcept C111368507 @default.
- W2291495588 hasConcept C115624301 @default.
- W2291495588 hasConcept C127313418 @default.
- W2291495588 hasConcept C155647269 @default.
- W2291495588 hasConcept C161790260 @default.
- W2291495588 hasConcept C163638829 @default.
- W2291495588 hasConcept C178516000 @default.
- W2291495588 hasConcept C178790620 @default.
- W2291495588 hasConcept C185592680 @default.
- W2291495588 hasConcept C2777289219 @default.
- W2291495588 hasConcept C2778421718 @default.
- W2291495588 hasConcept C2779692420 @default.
- W2291495588 hasConcept C2779825165 @default.
- W2291495588 hasConcept C32909587 @default.
- W2291495588 hasConcept C50027330 @default.
- W2291495588 hasConcept C5304478 @default.
- W2291495588 hasConcept C541565711 @default.
- W2291495588 hasConcept C66009135 @default.
- W2291495588 hasConcept C75473681 @default.
- W2291495588 hasConceptScore W2291495588C108204754 @default.
- W2291495588 hasConceptScore W2291495588C111368507 @default.
- W2291495588 hasConceptScore W2291495588C115624301 @default.
- W2291495588 hasConceptScore W2291495588C127313418 @default.