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- W2292082013 abstract "Abstract Highly active and stable MoS 2 /carbon hierarchical spheres with abundant active edge sites were fabricated by a simple micro-emulsion procedure where PVP was used as the carbon source, and carbon disulfide as the sulfur source and oil phase in micro-emulsion to control the morphology of MoS 2 . Hierarchical spheres of MoS 2 /carbon with a diameter of ca. 500 nm were obtained and characterized by scanning and transmission electron microscopic measurements. With a high electrochemically accessible surface area and defect-rich MoS 2 nanosheets, the MoS 2 /carbon hierarchical spheres exhibited an excellent electrocatalytic activity for hydrogen evolution reaction with a low onset potential of −103 mV (vs. RHE), small Tafel of 56.1 mV dec −1 , as well as extraordinary catalytic stability. The results were accounted for by the “inverted molybdenum reaction” that served as a novel way of regulating Mo catalytic sites of MoS 2 electrocatalysts." @default.
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- W2292082013 date "2016-04-01" @default.
- W2292082013 modified "2023-10-13" @default.
- W2292082013 title "Hierarchical spheres constructed by defect-rich MoS 2 /carbon nanosheets for efficient electrocatalytic hydrogen evolution" @default.
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- W2292082013 doi "https://doi.org/10.1016/j.nanoen.2016.02.056" @default.
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