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- W2292217714 abstract "AbstractThe effect of reducing the molar mass of the shell layer of core–shell latex particles on film-forming and final coating properties of self-crosslinking latexes was investigated. Latex particles were prepared by the semi-continuous non-seeded emulsion polymerization of methyl methacrylate, butyl acrylate and methacrylic acid as main monomers. The particle core was slightly cross-linked (using a constant amount of allyl methacrylate as a comonomer) to prevent the copolymers forming the core phase from migration into the shell phase. For interfacial cross-linking, diacetone acrylamide was copolymerized into the shell layer of latex particles to provide sites for subsequent reaction with adipic acid dihydrazide. The molar mass of copolymers forming the shell layer was systematically varied by isooctyl 3-mercaptopropionate chain transfer agent included in the synthesis of each of the shell layers and the molar mass distribution was determined using size exclusion chromatography coupled with a multi-an..." @default.
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- W2292217714 date "2016-02-01" @default.
- W2292217714 modified "2023-10-18" @default.
- W2292217714 title "Investigation of the effect of molar mass on coating properties of self-crosslinking latexes based on acrylic microgels" @default.
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- W2292217714 doi "https://doi.org/10.1080/01694243.2016.1140108" @default.
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