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- W2292555216 abstract "An oxidative rearrangement reaction of spiro tetrahydroisoquinolines has been developed for the synthesis of fused tetrahydroisoquinolines using in situ generated N-chloroamines. The reaction proceeds via initial chlorination of an amine, followed by a 1,2-carbon to nitrogen migration, and nucleophilic trapping of a ketiminium ion intermediate in a one-pot operation. The electrophilic nature of N-chloroamines allowed for the carbon–nitrogen bond formation in this reation." @default.
- W2292555216 created "2016-06-24" @default.
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- W2292555216 date "2016-03-01" @default.
- W2292555216 modified "2023-09-24" @default.
- W2292555216 title "Oxidative Rearrangement via in Situ Generated <i>N</i>-Chloroamine: Synthesis of Fused Tetrahydroisoquinolines" @default.
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- W2292555216 doi "https://doi.org/10.1021/acs.orglett.6b00233" @default.
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