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- W2292925505 abstract "Abstract Reagent‐controlled chemo‐ and regioselective reduction of 5,15‐diazaporphyrins has been developed. The selective reduction of carbon–carbon double bonds of diazaporphyrins provides 18 π aromatic isobacteriochlorin‐type products, whereas the reduction of carbon–nitrogen double bonds leads to selective formation of 20 π N , N ′‐dihydrodiazaporphyrins in excellent yields. The distinct antiaromatic character of N , N ′‐dihydrodiazaporphyrins has been revealed. The free‐base N , N ′‐dihydrodiazaporphyrin exhibits slower inner NH tautomerism than that in the corresponding 18 π porphyrins." @default.
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- W2292925505 date "2016-02-03" @default.
- W2292925505 modified "2023-10-01" @default.
- W2292925505 title "Chemo- and Regioselective Reduction of 5,15-Diazaporphyrins Providing Antiaromatic Azaporphyrinoids" @default.
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- W2292925505 doi "https://doi.org/10.1002/chem.201600066" @default.
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