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- W2293462637 abstract "Studies of europium and terbium complexing with lactic acid at 1 x 10/ sup -3/ to 3.98 x 10/sup -2/ M showed the existence of STAMA!/sup 2+/ at an acid concentration of 1 x 10/sup -3/ to 3.2 x 10/sup -3/ M; STAMA/sub 2/!/sup +/ at 3.2 x 10/sup -3/ to 9.6 x 10/sup -3/ M, and STAMA/sub 3/!/sup 0/ at 9.6 x 10/sup - 3/ to 4 x 10/sup -2/ M. The instability constants for the Eu complexes were: K/ sub 1-0/ = 3.7 x 10/sup -3/, K/sub 2-0/ = 2.6 x 10/sup -5/; an d K/sub 3-0/ = 4.8 x 10/sup -6/, while the stepwise instability constants were: K/sub 1-0/ = 3.7 x 10/sup -3/, K/sub 2-1/ = 7 x 10/sup -3/, and K/sub 3-2/ = 1.86 x 10/sup -1/. The Tb complexes with lactic acid at acid concentration from 8.6 x 10/sup -4/ to 4.3 x 10/sup -2/ M were: STAMA!/sup 2+/ at 8.6 x 10/sup -4/ to 3.99 x 10-/sup 3/ M; STAMA/sub 2/!/sup +/ at 3.99 x 10/sup -3/ to 9.6 x 10/sup -3/ M, and STAMA/sub 3/ !/sup 0/ at 9.6 x 10/sup -3/ to 4.35 x 10/sup -2/ M. The instabili ty constantsmore » for the Tb complexes were: K/sub 1-0/ = 3.0 x 10/sup -3/, K/sub 2-0/ = 4.1 x 10/ sup -5/, and K/sub 3-0/ = 7.7 x 10/sup -5/, and the stepwi se instability constants were caliculated as: K/sub 1-0/ = 3.0 x 10/sup -3/ K/sub 2-1/ = 1.35 X 10/sup -2/, and K/sub 3-2/ = 1.88. (R.V.J.)« less" @default.
- W2293462637 created "2016-06-24" @default.
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- W2293462637 date "1963-01-01" @default.
- W2293462637 modified "2023-09-26" @default.
- W2293462637 title "APPLICATION OF ION EXCHANGE TO STUDIES OF SUBSTANCE STATE IN SOLUTION. X. STUDIES OF EUROPIUM AND TERBIUM COMPLEXES WITH LACTIC ACID" @default.
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