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- W2294291248 abstract "Fine-tuning of the reaction between alkali metal siloxanolate [PhSi(O)ONa]n and [Ni(NH3)6]Cl2 allowed us to design new hexa- [(PhSiO1,5)12(NiO)6(H2O)(DMSO)9] () and pentanuclear [(PhSiO1,5)10(NiO)5(NaOH)(DMF)7] () cage-like silsesquioxanes. Their specific structures were studied by single crystal X-ray diffraction and topological analyses. Compound is the first example of a pentanuclear cylinder-like metallasilsesquioxane. Magnetic property investigations demonstrate the presence of a slow relaxation of the magnetization, induced by spin glass-like behavior in both cases." @default.
- W2294291248 created "2016-06-24" @default.
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- W2294291248 date "2016-01-01" @default.
- W2294291248 modified "2023-10-13" @default.
- W2294291248 title "Unusual penta- and hexanuclear Ni(<scp>ii</scp>)-based silsesquioxane polynuclear complexes" @default.
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- W2294291248 doi "https://doi.org/10.1039/c6dt00113k" @default.
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