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- W229430009 abstract "The asymmetric unit of the title compound, [Cd3(C8H5N2O2)2(SO4)2(H2O)3]n, contains three CdII ions, two sulfate anions, two 1H-benzimidazole-5-carboxylate (H2bic) ligands and three coordinated water molecules. One CdII ion is six-coordinated and exhibits a distorted octahedral geometry, while the other two CdII ions are seven-coordinated, displaying a distorted pentagonal–bipyramidal geometry. The CdII ions are bridged by two types of sulfate anions, producing inorganic chains along [100]. These chains are further connected by the H2bic ligands, leading to a three-dimensional framework. N—H⋯O and O—H⋯O hydrogen bonds and π–π interactions between the imidazole and benzene rings [centroid–centroid distances = 3.953 (2), 3.507 (2), 3.407 (2) and 3.561 (2) Å] further stabilize the crystal structure." @default.
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- W229430009 date "2011-08-27" @default.
- W229430009 modified "2023-09-23" @default.
- W229430009 title "Poly[μ-aqua-diaqua(μ<sub>3</sub>-1<i>H</i>-benzimidazole-5-carboxylato-κ<sup>3</sup><i>N</i><sup>3</sup>:<i>O</i>,<i>O</i>′)(μ<sub>2</sub>-1<i>H</i>-benzimidazole-5-carboxylato-κ<sup>3</sup><i>N</i><sup>3</sup>:<i>O</i>:<i>O</i>′)-μ<sub>5</sub>-sulfato-μ<sub>4</sub>-sulfato-tricadmium]" @default.
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- W229430009 doi "https://doi.org/10.1107/s1600536811034477" @default.
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