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- W2294590176 abstract "ABSTRACTLike bulk, Co1–xFexS2 nanoparticles also display an anomaly at x = 0.5. The borderline contiguous Co1–xFexS2 (x = 0.4 and 0.5) nanoparticles were synthesized with colloidal method and characterized for pyrite structure using various techniques, viz., X-ray diffraction, energy dispersive X-ray analysis (EDAX), S K-edge X-ray absorption near edge spectra, transmission electron microscopy (TEM) and Fourier transformed infra-red spectroscopy. The report presents the effect of high pressure on the borderline compositions using the Mossbauer spectroscopic and electrical resistivity techniques. Magnetic measurements on the system showed drastic lowering of Tc due to nanosize of the particles. With increased pressure, quadrupole splitting showed an expected trend of increase to attain a peak representing a second-order phase transition between 4 and 5 GPa for both the compositions. The pressure coefficient of electrical resistivity varied from –0.02 GPa to –0.06 GPa across transition pressure indicating a..." @default.
- W2294590176 created "2016-06-24" @default.
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- W2294590176 date "2016-03-04" @default.
- W2294590176 modified "2023-09-24" @default.
- W2294590176 title "High-pressure studies on nanocrystalline borderline Co1–xFexS2 (x = 0.4 and 0.5) using Mössbauer spectroscopic and electrical resistivity techniques up to 8 GPa" @default.
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- W2294590176 doi "https://doi.org/10.1080/01411594.2016.1156112" @default.
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