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- W2294666074 abstract "Study of the removal of blocking groups in redox polymer precursors, poly(5-vinyl-1,3-benzodioxole)(polymer 1) and poly(2,3-dimethoxystyrene) (polymer II), was undertaken with different acidic reagents. Boron trichloride dodecyl mercaptan (RSH) system showed a better cleaving performance among the experimented reagents. Poly(4-vinylcatechol), initially methanol- soluble, became purple-coloured with a defied insolubility under aerobic conditions. Intramolecular cross-linking is viewed as a possible explanation for the observed insolubility of the obtained resin ; that is, either benzene rings of two moieties undergo an intramolecular Pummerer reaction . A mechanism of the deportation of the redox polymers seems to besubstituent-dependent polymer precursors. Indeed. poly(3-vinylcatechol)remained methanol-soluble for months with a faint pink colour . Redox midpotentials of poly(3-vinyl- catechol) were established to be 707 mV at 23'C, while that of catechol was found to be 764mV under thesame conditions." @default.
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- W2294666074 date "2001-01-01" @default.
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- W2294666074 title "Redox Polymer Precursors : Removal of Blocking Groups and Redox Properties" @default.
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