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- W2295005655 abstract "The formation process of the spinel phase by the melt-impregnation method was extensively investigated by the pore volume distribution measurement. Two kinds of the spinel structure compounds Li{sub 1+x}Mn{sub 2}O{sub 4} optimized in this method were examined as a 4V cathode in a lithium nonaqueous cell. The first one has an initial charge capacity of 135--147 mAh/g and an unstable rechargeability with the characteristic two-step process, and another one delivers a slightly lower capacity of 105--120 mAh/g and ideal rechargeability with the quasi-one step process. These compounds preserve a capacity of more than 110 mAh/g for the first 100 cycles. The capacity fading on cycling of the former spinel only occurs at the second charge plateau in the rage of x < 0.4 in Li{sub x}Mn{sub 2}O{sub 4}, and is due to the unstable two-phase structure for lithium intercalation coexisting in this region. The excellent rechargeability for the later spinel results from a homogeneous reaction occurring over the entire intercalated region." @default.
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- W2295005655 date "1995-12-31" @default.
- W2295005655 modified "2023-09-27" @default.
- W2295005655 title "Dependence of battery performance of spinel Li{sub 1+x}Mn{sub 2}O{sub 4} on the preparation method" @default.
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